Ca<sup>2+</sup> Electrochemical\nIntercalation in Fe[Fe(CN)<sub>6</sub>]<sub>1–<i>y</i></sub> Berlin Green

Fe[Fe(CN)<sub>6</sub>]<sub>0.83</sub>·2.1 H<sub>2</sub>O has\nbeen prepared by precipitation and exhibits a cubic crystal structure\n(<i>Fm</i>3̅<i>m</i>, <i>a</i> = 10.1896(8) Å). Reversible redox activity in cells containing\neither sodium or calcium based electrolytes (capacity around 100 mAh/g)\ninduces structural changes that have been followed by <i>operando</i> synchrotron X-ray diffraction.

Publication Details

Journal
Figshare
Published
2024-12-23
DOI
https://doi.org/10.1021/acsaem.4c02623.s001
Primary Topic
Magnetism in coordination complexes
Type
article
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Ca2+ Electrochemical\nIntercalation in Fe[Fe(CN)6]1–y Berlin Green

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Magnetism in coordination complexes
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Ca2+ Electrochemical\nIntercalation in Fe[Fe(CN)6]1–y Berlin Green

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Abstract

Fe[Fe(CN)<sub>6</sub>]<sub>0.83</sub>·2.1 H<sub>2</sub>O has\nbeen prepared by precipitation and exhibits a cubic crystal structure\n(<i>Fm</i>3̅<i>m</i>, <i>a</i> = 10.1896(8) Å). Reversible redox activity in cells containing\neither sodium or calcium based electrolytes (capacity around 100 mAh/g)\ninduces structural changes that have been followed by <i>operando</i> synchrotron X-ray diffraction.

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Magnetism in coordination complexes
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Ca<sup>2+</sup> Electrochemical\nIntercalation in Fe[Fe(CN)<sub>6</sub>]<sub>1–<i>y</i></sub> Berlin Green · Figshare (2024) | TGRS Research Map | TGRS