Flash Communication:\nNickel-Mediated Cyclotetramerization\nof Phenylacetylene to 1,2-Dihydropentalenylnickel Complex

The reactions of phenylacetylene with [MesNN]Ni(2,4-lutidine)\n([MesNN]\n= 2,4-bis(mesitylimido)pentyl) (<b>1</b>) has been found to\ngive 1,2-dihydropentalenylnickel complex [MesNN]Ni(η<sup>3</sup>-Ph<sub>4</sub>C<sub>8</sub>H<sub>3</sub>) (complex <b>2</b>). The structure was determined by single-crystal X-ray diffraction\nanalysis.

Publication Details

Journal
Figshare
Published
2024-10-25
DOI
https://doi.org/10.1021/acs.organomet.4c00386.s001
Primary Topic
Synthesis and characterization of novel inorganic/organometallic compounds
Type
article
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Flash Communication:\nNickel-Mediated Cyclotetramerization\nof Phenylacetylene to 1,2-Dihydropentalenylnickel Complex

Figshare
Synthesis and characterization of novel inorganic/organometallic compounds
article

Flash Communication:\nNickel-Mediated Cyclotetramerization\nof Phenylacetylene to 1,2-Dihydropentalenylnickel Complex

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Abstract

The reactions of phenylacetylene with [MesNN]Ni(2,4-lutidine)\n([MesNN]\n= 2,4-bis(mesitylimido)pentyl) (<b>1</b>) has been found to\ngive 1,2-dihydropentalenylnickel complex [MesNN]Ni(η<sup>3</sup>-Ph<sub>4</sub>C<sub>8</sub>H<sub>3</sub>) (complex <b>2</b>). The structure was determined by single-crystal X-ray diffraction\nanalysis.

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Synthesis and characterization of novel inorganic/organometallic compounds
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Flash Communication:\nNickel-Mediated Cyclotetramerization\nof Phenylacetylene to 1,2-Dihydropentalenylnickel Complex · Figshare (2024) | TGRS Research Map | TGRS