Modularly Precise Construction of B,N-Embedded Large-Sized\nPolycyclic Aromatic Hydrocarbon Nanographene
A modular\n“fjord-stitching” reverse strategy has\nbeen disclosed to successfully prepare two large-sized B,N-embedded\nnanographenes: BN-TBTi and BN-TBTo. These two compounds both exhibit\nexcellent stability, nonzero-bandgap and decent photoluminescence\nquantum yield. Single crystal structure of BN-TBTo features a large\nC<sub>78</sub>B<sub>2</sub>N<sub>4</sub> π-skeleton with length\nand width of approximately 2.4 and 1.5 nm, respectively.
Publication Details
- Journal
- Figshare
- Published
- 2024-09-04
- DOI
- https://doi.org/10.1021/acs.orglett.4c02611.s001
- Primary Topic
- Organoboron and organosilicon chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.00