Modularly Precise Construction of B,N-Embedded Large-Sized\nPolycyclic Aromatic Hydrocarbon Nanographene

A modular\n“fjord-stitching” reverse strategy has\nbeen disclosed to successfully prepare two large-sized B,N-embedded\nnanographenes: BN-TBTi and BN-TBTo. These two compounds both exhibit\nexcellent stability, nonzero-bandgap and decent photoluminescence\nquantum yield. Single crystal structure of BN-TBTo features a large\nC<sub>78</sub>B<sub>2</sub>N<sub>4</sub> π-skeleton with length\nand width of approximately 2.4 and 1.5 nm, respectively.

Publication Details

Journal
Figshare
Published
2024-09-04
DOI
https://doi.org/10.1021/acs.orglett.4c02611.s001
Primary Topic
Organoboron and organosilicon chemistry
Type
article
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article

Modularly Precise Construction of B,N-Embedded Large-Sized\nPolycyclic Aromatic Hydrocarbon Nanographene

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Organoboron and organosilicon chemistry
article

Modularly Precise Construction of B,N-Embedded Large-Sized\nPolycyclic Aromatic Hydrocarbon Nanographene

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Abstract

A modular\n“fjord-stitching” reverse strategy has\nbeen disclosed to successfully prepare two large-sized B,N-embedded\nnanographenes: BN-TBTi and BN-TBTo. These two compounds both exhibit\nexcellent stability, nonzero-bandgap and decent photoluminescence\nquantum yield. Single crystal structure of BN-TBTo features a large\nC<sub>78</sub>B<sub>2</sub>N<sub>4</sub> π-skeleton with length\nand width of approximately 2.4 and 1.5 nm, respectively.

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Organoboron and organosilicon chemistry
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Modularly Precise Construction of B,N-Embedded Large-Sized\nPolycyclic Aromatic Hydrocarbon Nanographene · Figshare (2024) | TGRS Research Map | TGRS