Site-SelectiveRemote C4 Amination of 1‑Naphthamidesvia Palladium–Single-Electron Transfer Catalysis

Achieving site-selective remote C–H amination of polycyclic aromatic hydrocarbons is a challenging yet exciting goal. Herein, we report the remote C4 amination of electron-deficient 1-naphthamides through a single-electron transfer strategy. This protocol features excellent functional group compatibility and does not require a chelating auxiliary.

Publication Details

Journal
Figshare
Published
2025-02-07
DOI
https://doi.org/10.1021/acs.orglett.4c04858.s001
Primary Topic
Synthesis and Catalytic Reactions
Type
article
Field-Weighted Citation Impact
0.00
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article

Site-SelectiveRemote C4 Amination of 1‑Naphthamidesvia Palladium–Single-Electron Transfer Catalysis

Figshare
Synthesis and Catalytic Reactions
article

Site-SelectiveRemote C4 Amination of 1‑Naphthamidesvia Palladium–Single-Electron Transfer Catalysis

article en

Abstract

Achieving site-selective remote C–H amination of polycyclic aromatic hydrocarbons is a challenging yet exciting goal. Herein, we report the remote C4 amination of electron-deficient 1-naphthamides through a single-electron transfer strategy. This protocol features excellent functional group compatibility and does not require a chelating auxiliary.

Figshare
Openalex Percentile: Top 69%
Synthesis and Catalytic Reactions
DOISourceOpenAlex
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Site-SelectiveRemote C4 Amination of 1‑Naphthamidesvia Palladium–Single-Electron Transfer Catalysis · Figshare (2025) | TGRS Research Map | TGRS