Soft Wetting Ridge Rotation in Sessile Droplets andCapillary Bridges

We investigate the deformation of soft solid layers in the presence of sessile droplets or capillary bridges. Unlike models that assume Young’s law governs the contact angle, we incorporate the surface tension balance at the contact line to analyze the rotation of the wetting ridge and the corresponding change in the contact angle. Our findings reveal that the rotation direction of the wetting ridge aligns with the sign of the Laplace pressure. Interestingly, although a softer solid layer typically decreases the contact angle for sessile droplets, a negative Laplace pressure in a hydrophilic capillary bridge pulls the solid–liquid interface, leading to an increased contact angle. A hydrophilic capillary bridge would be expected to move from thicker regions of a soft layer to thinner areas, exhibiting behavior opposite that of a sessile droplet. The interplay between soft layer deformation and contact angle modulation provides valuable insights into controlling droplet motion through elastocapillarity.

Publication Details

Journal
Figshare
Published
2025-02-03
DOI
https://doi.org/10.1021/acs.langmuir.4c04667.s001
Primary Topic
Surface Modification and Superhydrophobicity
Type
article
Field-Weighted Citation Impact
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article

Soft Wetting Ridge Rotation in Sessile Droplets andCapillary Bridges

Figshare
Surface Modification and Superhydrophobicity
article

Soft Wetting Ridge Rotation in Sessile Droplets andCapillary Bridges

article en

Abstract

We investigate the deformation of soft solid layers in the presence of sessile droplets or capillary bridges. Unlike models that assume Young’s law governs the contact angle, we incorporate the surface tension balance at the contact line to analyze the rotation of the wetting ridge and the corresponding change in the contact angle. Our findings reveal that the rotation direction of the wetting ridge aligns with the sign of the Laplace pressure. Interestingly, although a softer solid layer typically decreases the contact angle for sessile droplets, a negative Laplace pressure in a hydrophilic capillary bridge pulls the solid–liquid interface, leading to an increased contact angle. A hydrophilic capillary bridge would be expected to move from thicker regions of a soft layer to thinner areas, exhibiting behavior opposite that of a sessile droplet. The interplay between soft layer deformation and contact angle modulation provides valuable insights into controlling droplet motion through elastocapillarity.

Figshare
Openalex Percentile: Top 62%
Surface Modification and Superhydrophobicity
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