Nickel-CatalyzedandTetrahydroxydiboron-MediatedAllylation of Aldehydes with Allyl Alcohols

The allylation of carbonyl compounds to form homoallylic alcohols represents one of the significant synthetic transformations. In this letter, we describe a new method for the allylation of aldehydes with allyl alcohols facilitated by nickel chloride and tetrahydroxydiboron. This approach offers a mild and straightforward procedure for the synthesis of homoallylic alcohols from aldehydes and ketones.

Publication Details

Journal
Figshare
Published
2025-02-03
DOI
https://doi.org/10.1021/acs.joc.4c02978.s001
Primary Topic
Organoboron and organosilicon chemistry
Type
article
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article

Nickel-CatalyzedandTetrahydroxydiboron-MediatedAllylation of Aldehydes with Allyl Alcohols

Figshare
Organoboron and organosilicon chemistry
article

Nickel-CatalyzedandTetrahydroxydiboron-MediatedAllylation of Aldehydes with Allyl Alcohols

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Abstract

The allylation of carbonyl compounds to form homoallylic alcohols represents one of the significant synthetic transformations. In this letter, we describe a new method for the allylation of aldehydes with allyl alcohols facilitated by nickel chloride and tetrahydroxydiboron. This approach offers a mild and straightforward procedure for the synthesis of homoallylic alcohols from aldehydes and ketones.

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Openalex Percentile: Top 69%
Organoboron and organosilicon chemistry
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Nickel-CatalyzedandTetrahydroxydiboron-MediatedAllylation of Aldehydes with Allyl Alcohols · Figshare (2025) | TGRS Research Map | TGRS