Photolysis of <i>bis</i>(catecholato)silicates

We investigated the chemical consequences of direct irradiation of alkyl <i>bis</i>(catecholato)silicates. We provide evidence for alkyl radical formation through EPR spin-trapping experiments, relative kinetics of radical formation, and direct observation of the nitro group-stabilized semiquinone radical.

Publication Details

Journal
Figshare
Published
2025-03-19
DOI
https://doi.org/10.1021/acs.joc.4c03072.s001
Primary Topic
Photochemistry and Electron Transfer Studies
Type
article
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article

Photolysis of bis(catecholato)silicates

Figshare
Photochemistry and Electron Transfer Studies
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Photolysis of bis(catecholato)silicates

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Abstract

We investigated the chemical consequences of direct irradiation of alkyl <i>bis</i>(catecholato)silicates. We provide evidence for alkyl radical formation through EPR spin-trapping experiments, relative kinetics of radical formation, and direct observation of the nitro group-stabilized semiquinone radical.

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Clean water and sanitation
Openalex Percentile: Top 63%
Photochemistry and Electron Transfer Studies
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Photolysis of <i>bis</i>(catecholato)silicates · Figshare (2025) | TGRS Research Map | TGRS