Calculation of Hyperfine Structure in Tm ii

The first measurements of the magnetic dipole hyperfine structure constants A in singly ionized thulium revealed substantial discrepancies with the corresponding theoretical calculations. Subsequent measurements expanded the very limited available dataset and demonstrated that two of the previously reported experimental A values were incorrect, thereby motivating new theoretical calculations. In this work, we employ the configuration interaction method to calculate the A constants for several low-lying levels in Tm ii, with the random-phase-approximation corrections also taken into account. Our results show good agreement with the new experimental data and provide reliable predictions for additional states where measurements are not yet available.

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Publication Details

Journal
Atoms
Published
2026-01-21
DOI
https://doi.org/10.3390/atoms14010007
Primary Topic
Atomic and Molecular Physics
Type
article
Field-Weighted Citation Impact
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article

Calculation of Hyperfine Structure in Tm ii

Atoms
Atomic and Molecular Physics
article

Calculation of Hyperfine Structure in Tm ii

article en

Abstract

The first measurements of the magnetic dipole hyperfine structure constants A in singly ionized thulium revealed substantial discrepancies with the corresponding theoretical calculations. Subsequent measurements expanded the very limited available dataset and demonstrated that two of the previously reported experimental A values were incorrect, thereby motivating new theoretical calculations. In this work, we employ the configuration interaction method to calculate the A constants for several low-lying levels in Tm ii, with the random-phase-approximation corrections also taken into account. Our results show good agreement with the new experimental data and provide reliable predictions for additional states where measurements are not yet available.

AtomsVol. 14(1)
Helmholtz Institute Jena (DE), GSI Helmholtz Centre for Heavy Ion Research (DE)
Openalex Percentile: Top 97%
Atomic and Molecular Physics
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