Microscopic Evidence of Spin-Driven Multiferroicity and Topological Spin Textures in Monolayer <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"> <mml:mrow> <mml:msub> <mml:mrow> <mml:mi>NiI</mml:mi> </mml:mrow> <mml:mrow> <mm

In type-II multiferroics, noncollinear spin textures are expected to induce electric polarization directly, leading to strong magnetoelectric coupling. Realizing such spin-driven multiferroicity in two-dimensional (2D) systems, and elucidating the interplay between local spins and electric polarization, are of both fundamental and technological importance. Here, using vectorial spin-polarized scanning tunneling microscopy, we investigated the spin-driven multiferroicity in monolayer NiI_{2} at atomic scale. We identify a canted spin-spiral state with fully determined spin rotation plane, accompanied by a 2Q charge modulation. At spin-spiral domain walls, we discover topological spin textures that are composed of meron-antimeron pairs. These textures are associated with a distinct charge pattern and notable band shifts, indicating local bound charges induced by variations of ferroelectricity at domain wall. Our observations are well captured by a realistic spin model incorporating Kitaev interactions and a generalized spin-current model of type-II multiferroicity. The findings provide microscopic evidence of spin-driven multiferroicity in an extreme 2D system and establish a platform for low-dissipation, electric-field control of topological spin textures.