Hydrogeochemical Characteristics and Groundwater Quality in Chengde Bashang Area, China

This study aims to investigate hydrogeochemical characteristics and groundwater quality in the Bashang Area in Chengde and to discuss factors controlling the groundwater quality. A total of 91 groundwater samples were collected and a fuzzy synthetic evaluation (FSE) method was used for assessing groundwater quality. Results show the groundwater chemistry in the study area is predominantly characterized by HCO3−-Ca type waters. Rock weathering processes dominate the hydrogeochemical processes within the study area, while also being influenced by evaporation and concentration effects. The results of the fuzzy evaluation indicate that 94.5% of groundwater samples are of good quality and suitable for drinking (Classes I, II, and III), while 5.5% are of poor quality and unsuitable for drinking (Class IV). Among these, bedrock fissure water exhibited superior quality. Within clastic rock pore water, elevated levels of NO3− and F− ions were observed in certain localized areas. The exceedance of NO3− concentrations stems from agricultural expansion, where the application of nitrogen fertilizers constitutes the primary driver of local nitrate pollution. Excessive F− levels correlate with the region’s indigenous geological background. Fluoride-bearing minerals such as fluorite and biotite are widely distributed throughout the study area. Intensive evaporation concentrates groundwater, while the region’s slow groundwater flow facilitates the accumulation and enrichment of F− within aquifers.