A crystalline chiral phosphide for the synthesis of the first P-stereogenic P( <scp>iii</scp> ) fluoride: a stable ligand for the Rh-catalyzed asymmetric arylation of isatins
Electrophilic fluorination of a crystalline phosphide yields the first stable P-stereogenic P( iii ) fluoride, which is an excellent ligand for asymmetric catalysis.
Authors
- Romano Dorta (ORCID: https://orcid.org/0000-0001-5986-9729)
- Frank W. Heinemann (ORCID: https://orcid.org/0000-0002-9007-8404)
- Giorgio Parla
- Alberto Herrera (ORCID: https://orcid.org/0000-0003-1947-9317)
- Laila Al Baridi
Institutions
- Friedrich-Alexander-Universität Erlangen-Nürnberg (DE)
Publication Details
- Journal
- Inorganic Chemistry Frontiers
- Published
- 2025-12-18
- DOI
- https://doi.org/10.1039/d5qi01994j
- Primary Topic
- Catalytic Cross-Coupling Reactions
- Type
- article
- Field-Weighted Citation Impact
- 0.00