Biochemical Reduction of Metal Salts as a Prominent Approach for Biohybrid Nanomaterials Production: A Review

Metal nanoparticles are unique materials with diverse properties and a wide range of paramount applications in various scientific fields, from catalysis and electrochemistry to pharmaceuticals and high-tech composite materials. Among the many methods for producing nanoparticles, those that use renewable plant biomass or its extracts, as well as biogenic approaches for synthesizing nanoparticles within living cells, are particularly promising from the viewpoint of Green Chemistry and sustainable development. These techniques, which are part of the rapidly growing field of Nanobiotechnology, can help solve problems associated with the use of toxic or expensive chemicals and increase the sustainability and affordability of the production of nanoparticles and biohybrid materials based on them. This review explores various methods for creating nanoparticles from both precious and base metals, using a variety of reducing agents and enzymes found in plants and bacteria, as well as promising biochemical approaches involving the reduction of metal salts inside living cells.