Burst laser-induced pitting (BLIP): transient defect–field interplay in ultrafast surface structuring

Abstract This study examines burst laser-induced pitting (BLIP), an understudied surface modification phenomenon driven by ultrafast laser bursts with sub-picosecond to picosecond inter-pulse delays. Through SEM and AFM analysis, we characterize BLIP as sub-micron pits with polarization-dependent oval shapes, alongside high-fluence melting zones and localized ripple-like structures. Unlike conventional laser-induced periodic surface structures (LIPSS), BLIP demonstrates exceptional energy coupling efficiency, evidenced by 10× greater damage areas and a steeper fluence-scaling expansion rate than LIPSS, attributed to transient carrier-mediated processes. Pit density decays exponentially with delay ( τ ≈ 6.6–8.9 ps), matching the timescale of self-trapped exciton relaxation, while spatial statistics reveal a delay-driven transition from field-guided ordering (1–5 ps) to randomized distributions (>10 ps). The resonant-like angular distributions and delay-dependent ellipticity reduction indicate competing mechanisms: optical field enhancement dominates at short delays, while energy dissipation and structure disordering prevail at longer delays. Simulation of nanoplasma excitation reveals near-field optical field enhancements responsible for the ellipticity and ripple-like structures. Beyond their fundamental significance, these BLIP nanostructures offer practical functionalities, including use as anti-reflection coatings and hydrophobic surfaces. These findings establish BLIP as a new paradigm in ultrafast laser-material interactions, where burst parameters selectively activate defect-mediated or field-driven modification pathways in dielectrics.