Iron-Catalyzed Synthesis of Primary Sulfinamidines from Sulfenamides
Unsubstituted primary sulfinamidines are obtained from sulfenamides by iron-catalyzed NH transfer from a readily available, shelf-stable hydroxylamine triflic acid salt. The reaction operates under mild conditions and does not require an inert atmosphere.
Authors
- Carsten Bolm (ORCID: https://orcid.org/0000-0001-9415-9917)
- Tianhao Zhang (ORCID: https://orcid.org/0009-0000-1733-3096)
- Shulei Pan
Institutions
- RWTH Aachen University (DE)
Publication Details
- Journal
- Organic Letters
- Published
- 2025-12-17
- DOI
- https://doi.org/10.1021/acs.orglett.5c04706
- Primary Topic
- Sulfur-Based Synthesis Techniques
- Type
- article
- Field-Weighted Citation Impact
- 0.00