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We successfully synthesized a novel intermetallic compound $\rm CrFe_2Ge_2$ with the $\rm Fe_{13}Ge_{8}$-type crystal structure. A structural study is presented combining single-crystal X-ray diffraction and Mössbauer spectroscopy analysis, confirming the presence of two distinct Fe sublattices. $\rm CrFe_2Ge_2$ exhibits a metallic ferromagnetic state with $T_C \approx \rm 200~K$. This material does not follow the usual $M^2 \propto H/M$ Arrott law, rather a modified Arrott law is obeyed in this material. The critical exponents determined from detailed analysis of modified Arrott plots were found to be $β= 0.392$, $γ= 1.309$ and $δ= 4.26$ obtained from the critical isotherm at $ T_{\rm C} =\rm 200~K$. Self-consistency and reliability of the critical exponent analysis were verified by the Widom scaling law and scaling equations. Using the results from renormalization group calculation, the critical behavior of $\rm CrFe_2Ge_2$ is akin to that of a $d=3, n=3$ ferromagnet in which the magnetic exhange distance is found to decay as $J(r) \approx r^{-4.86}$ with long-range magnetic coupling. The evaluated Rhodes-Wohlfarth ratio of $\sim 3$ points to an itinerant ferromagnetic ground state. Low-temperature measurements of resistivity, $p(T)$, and specific heat, $C_P(T)$, reveal a pronounced contribution from electron-magnon scattering.

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Publication Details

Journal
Journal of Magnetism and Magnetic Materials
Published
2025-12-17
DOI
https://doi.org/10.1016/j.jmmm.2025.173745
Primary Topic
Magnetic Properties of Alloys
Type
article
Field-Weighted Citation Impact
0.00

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Pedro Silva, Bruno J. C. Vieira, João C. Waerenborgh, J.A. Paixão et al.
Journal of Magnetism and Magnetic Materials
Magnetic Properties of Alloys
article

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Pedro Silva, Bruno J. C. Vieira, João C. Waerenborgh, J.A. Paixão, Phinifolo Cambalame
article en

Abstract

We successfully synthesized a novel intermetallic compound $\rm CrFe_2Ge_2$ with the $\rm Fe_{13}Ge_{8}$-type crystal structure. A structural study is presented combining single-crystal X-ray diffraction and Mössbauer spectroscopy analysis, confirming the presence of two distinct Fe sublattices. $\rm CrFe_2Ge_2$ exhibits a metallic ferromagnetic state with $T_C \approx \rm 200~K$. This material does not follow the usual $M^2 \propto H/M$ Arrott law, rather a modified Arrott law is obeyed in this material. The critical exponents determined from detailed analysis of modified Arrott plots were found to be $β= 0.392$, $γ= 1.309$ and $δ= 4.26$ obtained from the critical isotherm at $ T_{\rm C} =\rm 200~K$. Self-consistency and reliability of the critical exponent analysis were verified by the Widom scaling law and scaling equations. Using the results from renormalization group calculation, the critical behavior of $\rm CrFe_2Ge_2$ is akin to that of a $d=3, n=3$ ferromagnet in which the magnetic exhange distance is found to decay as $J(r) \approx r^{-4.86}$ with long-range magnetic coupling. The evaluated Rhodes-Wohlfarth ratio of $\sim 3$ points to an itinerant ferromagnetic ground state. Low-temperature measurements of resistivity, $p(T)$, and specific heat, $C_P(T)$, reveal a pronounced contribution from electron-magnon scattering.

Journal of Magnetism and Magnetic MaterialsVol. 639
Fundação para a Ciência e a Tecnologia
Openalex Percentile: Top 69%
Magnetic Properties of Alloys
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