<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" altimg="si162.svg" display="inline" id="d1e2117"> <mml:mrow> <mml:msub> <mml:mrow> <mml:mi mathvariant="normal">CrFe</mml:mi> </mml:mrow> <mml:mrow> <mml:mn>2</mml:mn> </mml:mrow> </mml:msub> <
We successfully synthesized a novel intermetallic compound $\rm CrFe_2Ge_2$ with the $\rm Fe_{13}Ge_{8}$-type crystal structure. A structural study is presented combining single-crystal X-ray diffraction and Mössbauer spectroscopy analysis, confirming the presence of two distinct Fe sublattices. $\rm CrFe_2Ge_2$ exhibits a metallic ferromagnetic state with $T_C \approx \rm 200~K$. This material does not follow the usual $M^2 \propto H/M$ Arrott law, rather a modified Arrott law is obeyed in this material. The critical exponents determined from detailed analysis of modified Arrott plots were found to be $β= 0.392$, $γ= 1.309$ and $δ= 4.26$ obtained from the critical isotherm at $ T_{\rm C} =\rm 200~K$. Self-consistency and reliability of the critical exponent analysis were verified by the Widom scaling law and scaling equations. Using the results from renormalization group calculation, the critical behavior of $\rm CrFe_2Ge_2$ is akin to that of a $d=3, n=3$ ferromagnet in which the magnetic exhange distance is found to decay as $J(r) \approx r^{-4.86}$ with long-range magnetic coupling. The evaluated Rhodes-Wohlfarth ratio of $\sim 3$ points to an itinerant ferromagnetic ground state. Low-temperature measurements of resistivity, $p(T)$, and specific heat, $C_P(T)$, reveal a pronounced contribution from electron-magnon scattering.
Authors
- Pedro Silva (ORCID: https://orcid.org/0000-0002-6760-4517)
- Bruno J. C. Vieira (ORCID: https://orcid.org/0000-0002-6536-9875)
- João C. Waerenborgh (ORCID: https://orcid.org/0000-0001-6171-4099)
- J.A. Paixão (ORCID: https://orcid.org/0000-0003-4634-7395)
- Phinifolo Cambalame (ORCID: https://orcid.org/0000-0002-6959-8931)
Publication Details
- Journal
- Journal of Magnetism and Magnetic Materials
- Published
- 2025-12-17
- DOI
- https://doi.org/10.1016/j.jmmm.2025.173745
- Primary Topic
- Magnetic Properties of Alloys
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Fundação para a Ciência e a Tecnologia