Spatially Tunable Interfacial Ferroelectricity in Low-Symmetric WTe <sub>2</sub>
Interfacial ferroelectricity, recently discovered in van der Waals (vdW) materials, exhibits switchable dipoles at the interface. Most experiments are realized by stacking high-symmetry two-dimensional (2D) lattices in specific stacking configurations. A prototype based on a synthetic and low-symmetry 2D lattice is robust for switchable dipoles with broken symmetry at the interface. Here, we show that interfacial ferroelectricity can be spatially tunable by controlling the odd-even layer number in the synthetic low-symmetry lattice of 1T'-WTe<sub>2</sub>. A high ferroelectric transition temperature (<i>T</i><sub>C</sub>) of >550 K is confirmed. The density functional theory (DFT) calculations indicate that interlayer sliding along the <i>b</i>-axis enables polarization switching of the interfacial dipoles. This study moves a significant step toward spatially tunable interfacial ferroelectricity.
Authors
- Erh‐Chen Lin
- Yi‐Hsien Lee (ORCID: https://orcid.org/0000-0002-0832-6369)
- Yuting Lin (ORCID: https://orcid.org/0000-0003-1894-8441)
- Shuzhen Fan (ORCID: https://orcid.org/0000-0002-4210-4129)
- Hsin Lin (ORCID: https://orcid.org/0000-0002-4688-2315)
- Hung‐Ju Tien (ORCID: https://orcid.org/0000-0002-3789-3928)
- Hao Zhu (ORCID: https://orcid.org/0000-0003-1596-4366)
- Chi Chen (ORCID: https://orcid.org/0000-0002-2880-7215)
- Hui Deng (ORCID: https://orcid.org/0000-0003-0629-3230)
- Shang‐Fan Lee (ORCID: https://orcid.org/0000-0001-5899-7200)
- Po‐Yen Liu (ORCID: https://orcid.org/0000-0003-3929-0730)
- Chun‐An Chen (ORCID: https://orcid.org/0000-0002-3400-9842)
- Chia-Seng Chang
- Che-Min Lin
- Tay-Rong Chang
- Ying‐Yu Lai
- Yi-Cheng Chiang
Institutions
- National Tsing Hua University (TW)
- University of Michigan (US)
- Research Center for Applied Science, Academia Sinica (TW)
- Joint Center for Quantum Information and Computer Science (US)
- Institute of Physics, Academia Sinica (TW)
- National Center for Theoretical Sciences (TW)
- National Center for Theoretical Sciences, Physics Division
- National Cheng Kung University (TW)
Publication Details
- Journal
- Nano Letters
- Published
- 2025-12-17
- DOI
- https://doi.org/10.1021/acs.nanolett.5c05610
- Citations
- 1
- Primary Topic
- 2D Materials and Applications
- Type
- article
- Field-Weighted Citation Impact
- 0.52