Recombination of HCO+ ions with electrons in the temperature range of 80–200 K

The recombination of HCO+ ions with electrons was studied in the temperature range of 80-200 K using a combination of stationary afterglow with CRDS and microwave diagnostic techniques. The determined recombination rate coefficient is αHCO+=(1.32±0.14)(300K/T)(0.52±0.14)×10-7 cm3 s-1. The pressure broadening coefficients for the P(4) transition of the 2000 ← 0000 vibrational band of HCO+ and the upper estimates for the reaction rate coefficient for the (HCO)+·CO cluster formation assisted by helium were also obtained.

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Journal
The Journal of Chemical Physics
Published
2025-12-17
DOI
https://doi.org/10.1063/5.0306395
Primary Topic
Spectroscopy and Laser Applications
Type
article
Field-Weighted Citation Impact
0.00

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article

Recombination of HCO+ ions with electrons in the temperature range of 80–200 K

Serhiy Rednyk, Štěpán Roučka, А. Д. Павлова, Miroslava Kassayová et al.
The Journal of Chemical Physics
Spectroscopy and Laser Applications
article

Recombination of HCO+ ions with electrons in the temperature range of 80–200 K

Serhiy Rednyk, Štěpán Roučka, А. Д. Павлова, Miroslava Kassayová, Petr Dohnal, J. Glosı́k, R. Plaŝil, S. van Houten, P. Slezák
article en

Abstract

The recombination of HCO+ ions with electrons was studied in the temperature range of 80-200 K using a combination of stationary afterglow with CRDS and microwave diagnostic techniques. The determined recombination rate coefficient is αHCO+=(1.32±0.14)(300K/T)(0.52±0.14)×10-7 cm3 s-1. The pressure broadening coefficients for the P(4) transition of the 2000 ← 0000 vibrational band of HCO+ and the upper estimates for the reaction rate coefficient for the (HCO)+·CO cluster formation assisted by helium were also obtained.

The Journal of Chemical PhysicsVol. 163(23)
Charles University (CZ)
Grantová Agentura České Republiky
Openalex Percentile: Top 64%
Spectroscopy and Laser Applications
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