A stable narrow-bandgap 2D iron–pyrazine framework exhibiting high photoconductivity and spin–charge coupling
We report a 2D coordination solid, (pyz)FeCl2, that combines semiconducting and magnetic properties. It exhibits a ∼1.0 eV band gap, high-spin Fe<sup>2+</sup>, and strong, stable photoconductivity with thermally activated, spin-dependent transport. Its robust stability and coupled spin-charge-light responses highlight its promise for next-generation 2D magneto-optoelectronic devices.
Authors
- Xianlei Huang
- Yan‐Zhen Zheng (ORCID: https://orcid.org/0000-0003-4056-097X)
- Mohamed Saber Lassoued (ORCID: https://orcid.org/0009-0000-4808-1709)
- Abid Hussain (ORCID: https://orcid.org/0000-0003-2310-2694)
Institutions
- Xi’an University (CN)
- Xi'an Jiaotong University (CN)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-12-09
- DOI
- https://doi.org/10.1039/d5cc06087g
- Primary Topic
- Magnetism in coordination complexes
- Type
- article
- Field-Weighted Citation Impact
- 0.00