Efficient selective hydrogenation of phenylacetylene over an intermetallic Ni–Sb catalyst

The development of efficient and cost-effective non-noble catalysts for selective hydrogenation of phenylacetylene remains a significant challenge. Herein, the prepared intermetallic NiSb phase displayed superior catalytic performance in selective hydrogenation of phenylacetylene in comparison with the Ni catalysts, with high styrene selectivity even at complete phenylacetylene conversion and excellent stability. Thus, the NiSb catalyst exhibited great potential as an alternative to Pd-based catalysts for phenylacetylene selective hydrogenation.

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Publication Details

Journal
Chemical Communications
Published
2025-12-09
DOI
https://doi.org/10.1039/d5cc06509g
Primary Topic
Catalysis for Biomass Conversion
Type
article
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article

Efficient selective hydrogenation of phenylacetylene over an intermetallic Ni–Sb catalyst

Mengxin Wang, Yinjie Deng, Shihong Zhou, Anjie Wang et al.
Chemical Communications
Catalysis for Biomass Conversion
article

Efficient selective hydrogenation of phenylacetylene over an intermetallic Ni–Sb catalyst

Mengxin Wang, Yinjie Deng, Shihong Zhou, Anjie Wang, Luxi Tan, Lichun Dong, Chenyang Lu, Aonan Zeng, Ling Qin, Fan Yao
article en

Abstract

The development of efficient and cost-effective non-noble catalysts for selective hydrogenation of phenylacetylene remains a significant challenge. Herein, the prepared intermetallic NiSb phase displayed superior catalytic performance in selective hydrogenation of phenylacetylene in comparison with the Ni catalysts, with high styrene selectivity even at complete phenylacetylene conversion and excellent stability. Thus, the NiSb catalyst exhibited great potential as an alternative to Pd-based catalysts for phenylacetylene selective hydrogenation.

Chemical CommunicationsVol. 62(4)
Chongqing University (CN), Dalian University of Technology (CN), Dalian University (CN), Chongqing University of Technology (CN)
Openalex Percentile: Top 60%
Catalysis for Biomass Conversion
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