Naphtha Production via Catalytic Hydrotreatment of Refined Residual Lipids: Validation in Industrially Relevant Scale

At the moment, there are no available data or studies exploring the production of naphtha boiling range hydrocarbons via hydroprocessing of pretreated residual lipids. To that aim, this study targets the production of naphtha, jet and diesel boiling range hydrocarbons via hydroprocessing of refined waste cooking oils utilizing solar hydrogen. The technology was first optimized in a TRL-3 plant. A heteroatom removal catalyst and a saturation catalyst were combined with an isomerization and hydrocracking catalyst to upgrade lipids. The results show that the severity of the process plays an important role in the yields of the fuels. Higher naphtha yields were observed at 663 K, 13.78 MPa and a liquid hourly space velocity of 0.33 h−1, leading to the production of a fuel consisting of 34 wt% naphtha, 23 wt% jet and 42 wt% diesel boiling range hydrocarbons. Subsequently, the technology was validated and demonstrated in an industrially relevant unit (TRL-5). The results from the fuel characterization show that the diesel fraction can be used as a high-quality road transport drop-in fuel, as it is characterized by a high cetane index (~96) and a high flash point (414 K). Although jet and naphtha meet most commercial fuel specifications, further optimization of the process is necessary to meet fuel standards. In conclusion, the current work provides novel data relevant to industrial applications for road, aviation and maritime fuel production via hydroprocessing of refined waste cooking oil.