ZnCl2-Activated Nanoporous Carbon Materials from Phyllanthus emblica Seed for High-Performance Supercapacitors
This study reports the synthesis of an activated nanoporous carbon material from Phyllanthus emblica (Amala)—a biomass material which is an eco-friendly, economical, and sustainable precursor used to prepare activated carbon using zinc chloride (ZnCl2) activation at various temperatures (500–700 °C) under a nitrogen gas atmosphere. A sample that was carbonized at 700 °C (AmC_Z700) attained a high specific surface area of 1436 m2 g−1 and a total pore volume of 0.962 cm3 g−1, and, when used in an electrode, showed excellent supercapacitance performance, attaining a high specific capacitance of 263 F g−1 at a current density of 1 A g−1, followed by 55% capacitance retention at 50 A g−1. Additionally, the assembled symmetric supercapacitor cell, when operated at 1.2 V, delivered an energy density of 8.9 Wh kg−1 at a power density of 300 W kg−1 and exhibited an excellent cycle life of 95% after 10,000 successive charge/discharge cycles, demonstrating the substantial potential of Phyllanthus emblica seed-derived carbon materials for the creation of high-performance supercapacitors.
Authors
- Rinita Rajbhandari
- Sabina Shahi (ORCID: https://orcid.org/0000-0002-9198-2470)
- Lok Kumar Shrestha (ORCID: https://orcid.org/0000-0003-2680-6291)
- Katsuhiko Ariga (ORCID: https://orcid.org/0000-0002-2445-2955)
- Rabindra Nath Acharyya (ORCID: https://orcid.org/0000-0002-5439-8937)
- Chhabi Lal Gnawali (ORCID: https://orcid.org/0000-0002-6554-1612)
- Sarita Manandhar (ORCID: https://orcid.org/0009-0001-4177-9693)
- Aabha Puri (ORCID: https://orcid.org/0009-0004-4103-7093)
Institutions
- University of Tsukuba (JP)
- Tribhuvan University (NP)
- National Institute for Materials Science (JP)
- Institute of Engineering (NP)
- The University of Tokyo (JP)
Publication Details
- Journal
- C – Journal of Carbon Research
- Published
- 2025-12-17
- DOI
- https://doi.org/10.3390/c11040095
- Primary Topic
- Supercapacitor Materials and Fabrication
- Type
- article
- Field-Weighted Citation Impact
- 0.00