Mechanistic insight into difunctionalization of aryl chlorides <i>via</i> palladium/phosphine ligand/norbornene cooperative catalysis
DFT calculations clarify the mechanism of Pd/phosphine ligand/norbornene-catalyzed aryl chloride difunctionalization, rationalizing chemoselectivity and the roles of norbornene and XPhos ligand.
Authors
- Xuexiang Ma (ORCID: https://orcid.org/0000-0002-0143-2732)
- Aili Feng (ORCID: https://orcid.org/0000-0002-3061-544X)
- Chao Shan
- Tingting Zhang (ORCID: https://orcid.org/0009-0002-0367-3799)
- Yu‐Sheng Liu (ORCID: https://orcid.org/0000-0002-7369-4168)
- Dongju Zhang (ORCID: https://orcid.org/0000-0002-6117-4958)
Institutions
- American Petroleum Institute (US)
- Shandong University (CN)
- Heze Medical College (CN)
- Heze University (CN)
Publication Details
- Journal
- Catalysis Science & Technology
- Published
- 2025-12-17
- DOI
- https://doi.org/10.1039/d5cy01147g
- Primary Topic
- Catalytic Cross-Coupling Reactions
- Type
- article
- Field-Weighted Citation Impact
- 0.00