Topologically enhanced exciton transport

Excitons dominate the optoelectronic response of many materials. Depending on the time scale and host material, excitons can exhibit free diffusion, phonon-limited diffusion, or polaronic diffusion, and exciton transport often limits the efficiency of optoelectronic devices such as solar cells or photodetectors. We demonstrate that topological excitons exhibit enhanced diffusion in all transport regimes. Using quantum geometry, we find that topological excitons are generically larger and more dispersive than their trivial counterparts, promoting their diffusion. We apply this general theory to organic polyacene semiconductors and show that exciton transport increases up to fourfold when topological excitons are present. We also propose that non-uniform electric fields can be used to directly probe the quantum metric of excitons, providing a rare experimental window into a basic geometric feature of quantum states. Our results provide a new strategy to enhance exciton transport in semiconductors and reveal that mathematical ideas of topology and quantum geometry can be important ingredients in the design of next-generation optoelectronic technologies.

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Publication Details

Journal
Nature Communications
Published
2025-12-13
DOI
https://doi.org/10.1038/s41467-025-66276-9
Citations
1
Primary Topic
Topological Materials and Phenomena
Type
article
Field-Weighted Citation Impact
1.25

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article

Topologically enhanced exciton transport

Joshua J. P. Thompson, Wojciech J. Jankowski, Bartomeu Monserrat, Robert-Jan Slager
1 citations
Nature Communications
Topological Materials and Phenomena
1.25
article

Topologically enhanced exciton transport

Joshua J. P. Thompson, Wojciech J. Jankowski, Bartomeu Monserrat, Robert-Jan Slager
article en
1 citations

Abstract

Excitons dominate the optoelectronic response of many materials. Depending on the time scale and host material, excitons can exhibit free diffusion, phonon-limited diffusion, or polaronic diffusion, and exciton transport often limits the efficiency of optoelectronic devices such as solar cells or photodetectors. We demonstrate that topological excitons exhibit enhanced diffusion in all transport regimes. Using quantum geometry, we find that topological excitons are generically larger and more dispersive than their trivial counterparts, promoting their diffusion. We apply this general theory to organic polyacene semiconductors and show that exciton transport increases up to fourfold when topological excitons are present. We also propose that non-uniform electric fields can be used to directly probe the quantum metric of excitons, providing a rare experimental window into a basic geometric feature of quantum states. Our results provide a new strategy to enhance exciton transport in semiconductors and reveal that mathematical ideas of topology and quantum geometry can be important ingredients in the design of next-generation optoelectronic technologies.

Nature CommunicationsVol. 16(1)
University of Cambridge (GB), University of Manchester (GB)
UK Research and Innovation, University of Warwick, Engineering and Physical Sciences Research Council, Trinity College, University of Cambridge
Openalex Percentile: Top 15%
Topological Materials and Phenomena
1.25
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