Synthesis and Investigation of Bonding Scenario in a Bis(silaselenone)
The compounds containing SiSe bond, are rarely reported in the literature. Silaselenones are the class of compounds that possess SiSe bond. Herein, we report a bis(silaselenone) ( 3 ) that contains two SiSe bonds. The compound 3 was characterized by single‐crystal X‐ray diffraction, mass spectrometry, and NMR spectroscopy. The nature of bonding in compound 3 has been studied by employing natural bond orbital analysis and energy decomposition analysis‐natural orbital for chemical valence (EDA‐NOCV). The bonding analysis by employing EDA‐NOCV method showed that compound 3 possesses two electron sharing covalent sigma bonds between the silicon atoms of silylene and SiPh 2 group.
Authors
- Saroj Kumar Kushvaha (ORCID: https://orcid.org/0000-0003-2802-7160)
- Regine Herbst‐Irmer (ORCID: https://orcid.org/0000-0003-1700-4369)
- Dietmar Stalke (ORCID: https://orcid.org/0000-0003-4392-5751)
- Harsha S. Karnamkkott (ORCID: https://orcid.org/0000-0003-2651-1514)
- Kartik Chandra Mondal (ORCID: https://orcid.org/0000-0002-5830-3608)
- Herbert W. Roesky (ORCID: https://orcid.org/0000-0003-4454-1434)
- Paula Kallenbach (ORCID: https://orcid.org/0000-0002-6545-4375)
- Sai Manoj N. V. T. Gorantla (ORCID: https://orcid.org/0000-0001-7315-6354)
Institutions
- Indian Institute of Technology Madras (IN)
- University of Göttingen (DE)
- UiT The Arctic University of Norway (NO)
Publication Details
- Journal
- European Journal of Inorganic Chemistry
- Published
- 2025-12-14
- DOI
- https://doi.org/10.1002/ejic.202500596
- Primary Topic
- Synthesis and characterization of novel inorganic/organometallic compounds
- Type
- article
- Field-Weighted Citation Impact
- 0.00