CeO <sub>2</sub> promotes oxygen vacancy generation in Co(OH) <sub>2</sub> for enhanced water oxidation

A comparative study of CeO<sub>2</sub>-decorated Co(OH)<sub>2</sub> and CoOOH highlights the critical role of substrate dynamics. Operando spectroscopic studies reveal that the interface derived from Co(OH)<sub>2</sub> efficiently stabilizes oxygen vacancies. Such vacancy stabilization promotes the formation of high-valent CoO<sub>2</sub> species, thereby enhancing oxygen evolution performance.

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Publication Details

Journal
Chemical Communications
Published
2025-12-09
DOI
https://doi.org/10.1039/d5cc06154g
Primary Topic
Electrocatalysts for Energy Conversion
Type
article
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article

CeO 2 promotes oxygen vacancy generation in Co(OH) 2 for enhanced water oxidation

Yanhong Liu, Pinxian Xi, Zidong He, Zhaori Mu et al.
Chemical Communications
Electrocatalysts for Energy Conversion
article

CeO 2 promotes oxygen vacancy generation in Co(OH) 2 for enhanced water oxidation

Yanhong Liu, Pinxian Xi, Zidong He, Zhaori Mu, Wei Shen, Peiqiong Li, Chun‐Hua Yan, Yunxiang Zhang
article en

Abstract

A comparative study of CeO<sub>2</sub>-decorated Co(OH)<sub>2</sub> and CoOOH highlights the critical role of substrate dynamics. Operando spectroscopic studies reveal that the interface derived from Co(OH)<sub>2</sub> efficiently stabilizes oxygen vacancies. Such vacancy stabilization promotes the formation of high-valent CoO<sub>2</sub> species, thereby enhancing oxygen evolution performance.

Chemical CommunicationsVol. 62(3)
Peking University (CN), Beijing National Laboratory for Molecular Sciences (CN), State Key Laboratory of Rare Earth Materials Chemistry and Application, Lanzhou University (CN), University of Hong Kong (HK)
Openalex Percentile: Top 70%
Electrocatalysts for Energy Conversion
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