Fluctuation theorems for autonomous work

Classical fluctuation theorems for work have been obtained theoretically, and verified experimentally, within a nonautonomous framework in which work is performed on a system of interest, [Formula: see text], by the external manipulation of a work parameter, such as a piston's position. Here, we obtain fluctuation theorems within an autonomous framework in which [Formula: see text] exchanges energy with a reversible work source, [Formula: see text]. The two subsystems, [Formula: see text] and [Formula: see text], interact with one another as they evolve under Hamiltonian or stochastic dynamics, without external intervention. In this setting, we must account for the backaction of [Formula: see text] on [Formula: see text], which is absent in the nonautonomous setting. We obtain autonomous versions of standard fluctuation theorems for work and entropy production. In each case, we argue, the autonomous fluctuation theorem reduces to its nonautonomous counterpart when [Formula: see text]'s inertia becomes infinitely large.

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Publication Details

Journal
Proceedings of the National Academy of Sciences
Published
2025-12-12
DOI
https://doi.org/10.1073/pnas.2524775122
Primary Topic
Advanced Thermodynamics and Statistical Mechanics
Type
article
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article

Fluctuation theorems for autonomous work

Saar Rahav, Christopher Jarzynski, Sebastian Deffner
Proceedings of the National Academy of Sciences
Advanced Thermodynamics and Statistical Mechanics
article

Fluctuation theorems for autonomous work

Saar Rahav, Christopher Jarzynski, Sebastian Deffner
article en

Abstract

Classical fluctuation theorems for work have been obtained theoretically, and verified experimentally, within a nonautonomous framework in which work is performed on a system of interest, [Formula: see text], by the external manipulation of a work parameter, such as a piston's position. Here, we obtain fluctuation theorems within an autonomous framework in which [Formula: see text] exchanges energy with a reversible work source, [Formula: see text]. The two subsystems, [Formula: see text] and [Formula: see text], interact with one another as they evolve under Hamiltonian or stochastic dynamics, without external intervention. In this setting, we must account for the backaction of [Formula: see text] on [Formula: see text], which is absent in the nonautonomous setting. We obtain autonomous versions of standard fluctuation theorems for work and entropy production. In each case, we argue, the autonomous fluctuation theorem reduces to its nonautonomous counterpart when [Formula: see text]'s inertia becomes infinitely large.

Proceedings of the National Academy of SciencesVol. 122(51)
Technion – Israel Institute of Technology (IL), Center for Physical Sciences and Technology (LT), Joint Center for Quantum Information and Computer Science (US), Joint Quantum Institute (US), Quantum Technologies (Sweden) (SE), University of Maryland, College Park (US), University of Maryland, Baltimore County (US)
Openalex Percentile: Top 68%
Advanced Thermodynamics and Statistical Mechanics
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Fluctuation theorems for autonomous work — Saar Rahav, Christopher Jarzynski, et al. · Proceedings of the National Academy of Sciences (2025) | TGRS Research Map | TGRS