Constructing highly reactive Pd nanoparticles with π bonds in imidazolium-based metal–organic frameworks for chemoselective CO <sub>2</sub> multicomponent transformation
A scalable π-bond-stabilized 10%Pd@Er-MOF catalyst drives 100% selective 4C-TCRs of propargylic amines, aryl iodides, and in situ -activated CO 2 , yielding oxazolidinones with 99% yield and 227 h −1 TOF.
Authors
- Guohai Xu (ORCID: https://orcid.org/0000-0003-1222-5613)
- Hongen Qu
- Zhonggao Zhou (ORCID: https://orcid.org/0000-0002-0003-2374)
- Shiyong Zhang (ORCID: https://orcid.org/0000-0001-7633-358X)
- Yiwang Chen (ORCID: https://orcid.org/0000-0003-4709-7623)
- Jie Chen (ORCID: https://orcid.org/0000-0003-4599-3600)
- Qinggang Zhang (ORCID: https://orcid.org/0000-0002-3921-9988)
- Lingfang Kong
- Wenjing Shi
Institutions
- Nanchang University (CN)
- Gannan Medical University (CN)
- Gannan Normal University (CN)
- Jiangxi University of Science and Technology (CN)
- Jiangxi Normal University (CN)
Publication Details
- Journal
- Green Chemistry
- Published
- 2025-12-13
- DOI
- https://doi.org/10.1039/d5gc04311e
- Primary Topic
- Carbon dioxide utilization in catalysis
- Type
- article
- Field-Weighted Citation Impact
- 0.00