A Critical Review of Diffusion—Thermomechanical and Composite Reinforcement Approaches for Surface Hardening of Aluminum Alloys and Matrix Composites

Aluminum alloys require improved surface performance to satisfy the demands of today’s aerospace, automotive, marine, and structural applications. This paper compares three key surface hardening methods: diffusion-assisted microalloying, thermomechanical deformation-based treatments, and composite/hybrid reinforcing procedures. Diffusion-assisted Zn/Mg enrichment allows for localized precipitation hardening but is limited by the native Al2O3 barrier, slow solute mobility, alloy-dependent solubility, and shallow hardened depths. In contrast, thermomechanical techniques such as shot peening, surface mechanical attrition treatment (SMAT), and laser shock peening produce ultrafine/nanocrystalline layers, high dislocation densities, and deep compressive residual stresses, allowing for predictable increases in hardness, fatigue resistance, and corrosion performance. Composite and hybrid reinforcement systems, such as SiC, B4C, graphene, and graphite-based aluminum matrix composites (AMCs), use load transfer, Orowan looping, interfacial strengthening, and solid lubrication effects to enhance wear resistance and through-thickness strengthening. Comparative evaluations show that, while diffusion-assisted procedures are still labor-intensive and solute-sensitive, thermomechanical treatments are more industrially established and scalable. Composite and hybrid systems provide the best tribological and load-bearing performance but necessitate more sophisticated processing approaches. Recent corrosion studies show that interfacial chemistry, precipitate distribution, and galvanic coupling all have a significant impact on pitting and stress corrosion cracking (SCC). These findings highlight the importance of treating corrosion as a fundamental design variable in all surface hardening techniques. This work uses unified tables and drawings to provide a thorough examination of strengthening mechanisms, corrosion and fatigue behavior, hardening depth, alloy suitability, and industrial feasibility. Future research focuses on overcoming diffusion barriers, establishing next-generation gradient topologies and hybrid processing approaches, improving strength ductility corrosion trade-offs, and utilizing machine-learning-guided alloy design. This research presents the first comprehensive framework for selecting multifunctional aluminum surfaces in demanding aerospace, automotive, and marine applications by seeing composite reinforcements as supplements rather than strict alternatives to diffusion-assisted and thermomechanical approaches.