Symmetric versus antisymmetric strain tuning of the valence transition in Yb( <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow> <mml:msub> <mml:mi>In</mml:mi> <mml:mrow> <mml:mn>1</mml:mn> <mml:mo>−</mml:mo> <mml:mi>x</mml:mi> </mm

Similar to transitions in a range of correlated quantum materials, the valence transition exhibits a strong coupling to the crystal lattice, rendering it highly sensitive to stress tuning. In the present work, we determine the effect of uniaxial stress, which breaks the lattice symmetry, on the valence transition temperature and its crossover temperature in pure and Ag-substituted <a:math xmlns:a="http://www.w3.org/1998/Math/MathML"> <a:msub> <a:mi>YbInCu</a:mi> <a:mn>4</a:mn> </a:msub> </a:math> . Our key result is that hydrostatic stress is more effective in tuning this transition than uniaxial stress. Based on a symmetry decomposition of the stress-induced strains, we argue that this observation can be quantitatively understood, given that the valence transition is mostly sensitive to symmetric strains and thus volume changes of the lattice. These results support the notion that the valence transition can give rise to critical elasticity close to its critical endpoint.

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Publication Details

Journal
Physical review. B./Physical review. B
Published
2025-11-25
DOI
https://doi.org/10.1103/3kf4-b534
Primary Topic
Rare-earth and actinide compounds
Type
article
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article

Symmetric versus antisymmetric strain tuning of the valence transition in Yb( <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow> <mml:msub> <mml:mi>In</mml:mi> <mml:mrow> <mml:mn>1</mml:mn> <mml:mo>−</mml:mo> <mml:mi>x</mml:mi> </mm

Karl J. Friston
Physical review. B./Physical review. B
Rare-earth and actinide compounds
article

Symmetric versus antisymmetric strain tuning of the valence transition in Yb( <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow> <mml:msub> <mml:mi>In</mml:mi> <mml:mrow> <mml:mn>1</mml:mn> <mml:mo>−</mml:mo> <mml:mi>x</mml:mi> </mm

Karl J. Friston
article en

Abstract

Similar to transitions in a range of correlated quantum materials, the valence transition exhibits a strong coupling to the crystal lattice, rendering it highly sensitive to stress tuning. In the present work, we determine the effect of uniaxial stress, which breaks the lattice symmetry, on the valence transition temperature and its crossover temperature in pure and Ag-substituted <a:math xmlns:a="http://www.w3.org/1998/Math/MathML"> <a:msub> <a:mi>YbInCu</a:mi> <a:mn>4</a:mn> </a:msub> </a:math> . Our key result is that hydrostatic stress is more effective in tuning this transition than uniaxial stress. Based on a symmetry decomposition of the stress-induced strains, we argue that this observation can be quantitatively understood, given that the valence transition is mostly sensitive to symmetric strains and thus volume changes of the lattice. These results support the notion that the valence transition can give rise to critical elasticity close to its critical endpoint.

Physical review. B./Physical review. BVol. 112(23)
Goethe University Frankfurt (DE), Goethe-Institute United Kingdom (GB), University of St Andrews (GB), Max Planck Institute for Chemical Physics of Solids (DE), Technische Universität Dresden (DE)
Openalex Percentile: Top 74%
Rare-earth and actinide compounds
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