Modeling optical formation of ultracold <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:msub> <mml:mi>NaK</mml:mi> <mml:mn>2</mml:mn> </mml:msub> </mml:math> ground-state molecules

We study the rovibronic transitions in <a:math xmlns:a="http://www.w3.org/1998/Math/MathML"> <a:msub> <a:mi>NaK</a:mi> <a:mn>2</a:mn> </a:msub> </a:math> between its electronic ground state <b:math xmlns:b="http://www.w3.org/1998/Math/MathML"> <b:mrow> <b:msup> <b:mn>1</b:mn> <b:mn>2</b:mn> </b:msup> <b:msup> <b:mi>A</b:mi> <b:mo>′</b:mo> </b:msup> </b:mrow> </b:math> and its second excited state <c:math xmlns:c="http://www.w3.org/1998/Math/MathML"> <c:mrow> <c:msup> <c:mn>3</c:mn> <c:mn>2</c:mn> </c:msup> <c:msup> <c:mi>A</c:mi> <c:mo>′</c:mo> </c:msup> </c:mrow> </c:math> , to identify possible pathways for the creation of ultracold ground-state triatomic molecules. Our methodology relies on the computation of potential energy surfaces and transition dipole moment surfaces for the relevant electronic states using methods. Rovibrational energy levels and wave functions are determined using the discrete variable representation approach. A double-well structure of the potential energy surface is identified for both states, and the related transition strengths between the rovibrational levels are derived. Our calculations show that the formation of ultracold ground-state <d:math xmlns:d="http://www.w3.org/1998/Math/MathML"> <d:msub> <d:mi>NaK</d:mi> <d:mn>2</d:mn> </d:msub> </d:math> molecules is expected when starting from an excited electronic state of <e:math xmlns:e="http://www.w3.org/1998/Math/MathML"> <e:msub> <e:mi>NaK</e:mi> <e:mn>2</e:mn> </e:msub> </e:math> , which can be created by photoassociation of NaK and K, as observed by optical means by Cao, [].