Synchronizing Excited-State Lifetimes for Bright and Long-Lived White Phosphorescent Carbon Nanodots
White phosphorescent materials are highly desirable for delayed lighting and advanced display applications; however, their development is hindered by time-dependent spectral changes and low efficiency. Herein, we report bright and long-lived white phosphorescence from carbon nanodots (CNDs) achieved by synchronizing excited-state lifetime engineering yielding white phosphorescent CNDs with a lifetime of 800 ms and a quantum efficiency of 27.9%. A secondary carbonization strategy synchronizes multiple emission centers, enabling stable white phosphorescence over 6 s, tunable correlated color temperature (4400-7990 K), and CIE coordinates (0.29, 0.32) to (0.36, 0.34). Moreover, integration of these CNDs into a light emitting diode (LED) demonstrates delayed white emission with suppressed flicker under alternating-current excitation, providing eye-friendly illumination. Programmable delayed LED arrays reconstruct temporally fragmented signals into coherent images. This work demonstrates a robust strategy for bright and long-lasting white phosphorescent materials, laying the foundation for advanced delayed lighting and programmable display applications.
Authors
- Mengdi Gao (ORCID: https://orcid.org/0000-0001-5462-0078)
- Shiyu Song (ORCID: https://orcid.org/0000-0001-8438-2277)
- Chaojun Gao
- Sitao Liu (ORCID: https://orcid.org/0000-0002-2969-2421)
- Wenshuo Zhang (ORCID: https://orcid.org/0000-0001-9643-0344)
- Chongxin Shan (ORCID: https://orcid.org/0000-0001-7119-5325)
- Xiangyu Li (ORCID: https://orcid.org/0000-0002-5722-0018)
- Wenbo Zhao (ORCID: https://orcid.org/0009-0000-3327-003X)
- Kai-Kai Liu (ORCID: https://orcid.org/0000-0002-1811-6699)
- Qing Cao (ORCID: https://orcid.org/0000-0001-7557-9799)
Institutions
- Zhengzhou University (CN)
- Henan Academy of Sciences (CN)
Publication Details
- Journal
- Nano Letters
- Published
- 2025-12-11
- DOI
- https://doi.org/10.1021/acs.nanolett.5c05349
- Primary Topic
- Carbon and Quantum Dots Applications
- Type
- article
- Field-Weighted Citation Impact
- 0.00