Photoinduced Tandem Oxidation/Ring-Opening of Cyclic Amines: Synthesis of 1,4-Naphthoquinone-Based Amino Benzaldehyde

A photoinduced ring-opening/oxidation tandem of cyclic amines without an external photocatalyst was developed and provided the corresponding 1,4-naphthoquinone-based amino benzaldehydes in good yields under mild conditions. Investigations indicated that this transformation process is by the tandem oxidation/ring-opening of cyclic amines under visible light (410 nm) irradiation.

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Publication Details

Journal
The Journal of Organic Chemistry
Published
2025-12-09
DOI
https://doi.org/10.1021/acs.joc.5c01575
Primary Topic
Radical Photochemical Reactions
Type
article
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article

Photoinduced Tandem Oxidation/Ring-Opening of Cyclic Amines: Synthesis of 1,4-Naphthoquinone-Based Amino Benzaldehyde

Jin‐Heng Li, Yonghui He, Desheng Wang, Yujie Shi et al.
The Journal of Organic Chemistry
Radical Photochemical Reactions
article

Photoinduced Tandem Oxidation/Ring-Opening of Cyclic Amines: Synthesis of 1,4-Naphthoquinone-Based Amino Benzaldehyde

Jin‐Heng Li, Yonghui He, Desheng Wang, Yujie Shi, Xiaojing Zhao, Yuan‐Feng Tong
article en

Abstract

A photoinduced ring-opening/oxidation tandem of cyclic amines without an external photocatalyst was developed and provided the corresponding 1,4-naphthoquinone-based amino benzaldehydes in good yields under mild conditions. Investigations indicated that this transformation process is by the tandem oxidation/ring-opening of cyclic amines under visible light (410 nm) irradiation.

The Journal of Organic ChemistryVol. 90(50)
Qingdao University of Science and Technology (CN), Minzu University of China (CN), State Ethnic Affairs Commission (CN), Institute for Ethnic Studies (SI)
Openalex Percentile: Top 70%
Radical Photochemical Reactions
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