Crystal structure and Hirshfeld surface analysis of (2 <i>Z</i> )-4-oxo-4-{phenyl[(2 <i>E</i> )-3-phenylprop-2-en-1-yl]amino}but-2-enoic acid

In the crystal structure of the title compound, C<sub>19</sub>H<sub>17</sub>NO<sub>3</sub>, C-H⋯O hydrogen bonds connect mol-ecular pairs to produce dimers with an <i>R</i> <sup>2</sup> <sub>2</sub>(16) ring motif. Additionally, C-H⋯π inter-actions form ribbons along the [101] direction. Van der Waals inter-actions between the ribbons help to consolidate the mol-ecular packing. Hirshfeld surface analysis shows that H⋯H (45.5%), C⋯H/H⋯C (30.4%), and O⋯H/H⋯O (19.3%) inter-actions are the main contributors to the crystal packing.

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Publication Details

Journal
Acta Crystallographica Section E Crystallographic Communications
Published
2025-12-03
DOI
https://doi.org/10.1107/s2056989025010746
Primary Topic
Crystal structures of chemical compounds
Type
article
Field-Weighted Citation Impact
0.00

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article

Crystal structure and Hirshfeld surface analysis of (2 Z )-4-oxo-4-{phenyl[(2 E )-3-phenylprop-2-en-1-yl]amino}but-2-enoic acid

Kseniia A. Alekseeva, Gizachew Mulugeta Manahelohe, Khudayar I. Hasanov, Mehmet Akkurt et al.
Acta Crystallographica Section E Crystallographic Communications
Crystal structures of chemical compounds
article

Crystal structure and Hirshfeld surface analysis of (2 Z )-4-oxo-4-{phenyl[(2 E )-3-phenylprop-2-en-1-yl]amino}but-2-enoic acid

Kseniia A. Alekseeva, Gizachew Mulugeta Manahelohe, Khudayar I. Hasanov, Mehmet Akkurt, Alexandra G. Kutasevich, Punhan J. Jamalov, Anna A. Zhernosek
article en

Abstract

In the crystal structure of the title compound, C<sub>19</sub>H<sub>17</sub>NO<sub>3</sub>, C-H⋯O hydrogen bonds connect mol-ecular pairs to produce dimers with an <i>R</i> <sup>2</sup> <sub>2</sub>(16) ring motif. Additionally, C-H⋯π inter-actions form ribbons along the [101] direction. Van der Waals inter-actions between the ribbons help to consolidate the mol-ecular packing. Hirshfeld surface analysis shows that H⋯H (45.5%), C⋯H/H⋯C (30.4%), and O⋯H/H⋯O (19.3%) inter-actions are the main contributors to the crystal packing.

Acta Crystallographica Section E Crystallographic CommunicationsVol. 82(1)
Peoples' Friendship University of Russia (RU), Azerbaijan Medical University (AZ), Russian New University (RU), Baku Engineering University (AZ), University of Gondar (ET), Erciyes University (TR)
RUDN University
Openalex Percentile: Top 67%
Crystal structures of chemical compounds
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