Vibrational model of entropy in dense two-dimensional fluids

A vibrational paradigm of atomic dynamic in dense fluids is known to provide useful insight on the transport and thermodynamic properties of fluids in three dimensions. In this paper, a vibrational model is generalized to describe the excess entropy of two-dimensional (2D) fluids. A simple practical implementation of this model is demonstrated to deliver accurate results for various systems, such as one-component plasmas with Coulomb and logarithmic interactions, a 2D fluid of dipole particles, and a 2D Yukawa fluid. The applicability limits, relevance to three-dimensional fluids, relations to other 2D phenomena, and potential practical applications are briefly discussed.

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Publication Details

Journal
Physical review. E
Published
2025-12-03
DOI
https://doi.org/10.1103/14db-xhrv
Primary Topic
Nanopore and Nanochannel Transport Studies
Type
article
Field-Weighted Citation Impact
0.00
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article

Vibrational model of entropy in dense two-dimensional fluids

Karl J. Friston
Physical review. E
Nanopore and Nanochannel Transport Studies
article

Vibrational model of entropy in dense two-dimensional fluids

Karl J. Friston
article en

Abstract

A vibrational paradigm of atomic dynamic in dense fluids is known to provide useful insight on the transport and thermodynamic properties of fluids in three dimensions. In this paper, a vibrational model is generalized to describe the excess entropy of two-dimensional (2D) fluids. A simple practical implementation of this model is demonstrated to deliver accurate results for various systems, such as one-component plasmas with Coulomb and logarithmic interactions, a 2D fluid of dipole particles, and a 2D Yukawa fluid. The applicability limits, relevance to three-dimensional fluids, relations to other 2D phenomena, and potential practical applications are briefly discussed.

Physical review. EVol. 113(1)
Joint Institute for High Temperatures (RU)
Openalex Percentile: Top 61%
Nanopore and Nanochannel Transport Studies
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