Interplay of phonons, intertwined density waves, and induced spin density wave in trilayer nickelates <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow> <mml:mi mathvariant="normal">P</mml:mi> <mml:msub> <mml:mi mathvariant="normal"

Lattice degrees of freedom (DoF) play a central role in correlated electron systems, strongly influencing the dynamics of the underlying charge carriers and spin excitations. In nickelates, understanding the role of lattice is essential to unravel the interplay between charge, orbital, and spin degrees of freedom in giving rise to various emergent phenomena reported recently. Here, we investigate the phononic DoF in a series of trilayer nickelates, namely $\mathrm{P}{\mathrm{r}}_{4\ensuremath{-}x}\mathrm{L}{\mathrm{a}}_{x}\mathrm{N}{\mathrm{i}}_{3}{\mathrm{O}}_{10}$ (where $x$ = 0, 0.4, 1, 2, 3.6, and 4) using temperature- and polarization-dependent Raman-scattering measurements. Our in-depth analysis of the phonon evolution with temperature and doping gives interesting insights into the behavior of these materials. All these systems undergo a metal-to-metal transition (${T}_{\mathrm{MMT}}$), characterized by the development of intertwined spin- and charge density waves. These transitions manifest as pronounced anomalies in phonon self-energy parameters, i.e., peak frequency and linewidth in the vicinity of the metal-to-metal transition. Several phonon modes show dramatic change (nearly an order of magnitude for some modes) in their softening rates across the ${T}_{\mathrm{MMT}}$, highlighting the sensitivity of the lattice dynamics to spin and charge order. These findings emphasize the crucial role of lattice DoF in mediating correlated ground states in layered nickelates.

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Publication Details

Journal
Physical review. B./Physical review. B
Published
2025-12-01
DOI
https://doi.org/10.1103/lg21-gcjs
Primary Topic
Magnetic and transport properties of perovskites and related materials
Type
article
Field-Weighted Citation Impact
0.00
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article

Interplay of phonons, intertwined density waves, and induced spin density wave in trilayer nickelates <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow> <mml:mi mathvariant="normal">P</mml:mi> <mml:msub> <mml:mi mathvariant="normal"

Karl J. Friston
Physical review. B./Physical review. B
Magnetic and transport properties of perovskites and related materials
article

Interplay of phonons, intertwined density waves, and induced spin density wave in trilayer nickelates <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow> <mml:mi mathvariant="normal">P</mml:mi> <mml:msub> <mml:mi mathvariant="normal"

Karl J. Friston
article en

Abstract

Lattice degrees of freedom (DoF) play a central role in correlated electron systems, strongly influencing the dynamics of the underlying charge carriers and spin excitations. In nickelates, understanding the role of lattice is essential to unravel the interplay between charge, orbital, and spin degrees of freedom in giving rise to various emergent phenomena reported recently. Here, we investigate the phononic DoF in a series of trilayer nickelates, namely $\mathrm{P}{\mathrm{r}}_{4\ensuremath{-}x}\mathrm{L}{\mathrm{a}}_{x}\mathrm{N}{\mathrm{i}}_{3}{\mathrm{O}}_{10}$ (where $x$ = 0, 0.4, 1, 2, 3.6, and 4) using temperature- and polarization-dependent Raman-scattering measurements. Our in-depth analysis of the phonon evolution with temperature and doping gives interesting insights into the behavior of these materials. All these systems undergo a metal-to-metal transition (${T}_{\mathrm{MMT}}$), characterized by the development of intertwined spin- and charge density waves. These transitions manifest as pronounced anomalies in phonon self-energy parameters, i.e., peak frequency and linewidth in the vicinity of the metal-to-metal transition. Several phonon modes show dramatic change (nearly an order of magnitude for some modes) in their softening rates across the ${T}_{\mathrm{MMT}}$, highlighting the sensitivity of the lattice dynamics to spin and charge order. These findings emphasize the crucial role of lattice DoF in mediating correlated ground states in layered nickelates.

Physical review. B./Physical review. BVol. 112(23)
Indian Institute of Science Education and Research Pune (IN), Indian Institute of Technology Kanpur (IN), Indian Institute of Technology Mandi (IN)
Openalex Percentile: Top 71%
Magnetic and transport properties of perovskites and related materials
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