Advanced halide/sulfide all-solid-state lithium metal batteries with fluorinated interface layer

The development of solid-state batteries is often hindered by interfacial instability, particularly between the electrolyte and the lithium metal anode. To address this challenge, we fabricate a bilayer solid-state electrolyte composed of Li₃InCl₆ and Li₆PS₅Cl, which demonstrates excellent mutual compatibility and high ionic conductivity. Furthermore, a robust, LiF-rich solid electrolyte interphase (SEI) was pre-formed on the lithium metal anode <i>via</i> a pre-treatment strategy in a fluoroethylene carbonate-containing electrolyte. This dual design not only ensures stable interfacial contact but also effectively suppresses interfacial side reactions. When integrated into an all-solid-state lithium metal battery with a LiCoO₂ cathode, the assembled cell delivers exceptional cycling stability, retaining over 85% of its initial capacity after 100 cycles at a rate of 0.2C. This work highlights the synergistic role of a compatible bilayer electrolyte and an artificial LiF-rich SEI in enabling high-performance and long-lasting solid-state lithium metal batteries.