Formation of Pyramidal Palladium Enhanced by B(C <sub>6</sub> F <sub>5</sub> ) <sub>3</sub> Additive Enabling Selective Alkene Monoisomerization

The addition of a strong Lewis acid, tris-(pentafluorophenyl)-borane, facilitates the reduction of Pd-(cod)-Cl<sub>2</sub> with Et<sub>3</sub>SiH to form palladium nanoparticles in organic solvents. It was found that these palladium nanoparticles are capable of selective monoisomerization of linear alkenes. This heterogeneous palladium catalyst is tolerant of a wide variety of functional groups, confirmed by substrate and robustness screenings. It is also possible to utilize poly-(methylhydro)-siloxane, an industrial waste byproduct, as the reductant to enable similar isomerization chemistry.

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Publication Details

Journal
ACS Omega
Published
2025-12-09
DOI
https://doi.org/10.1021/acsomega.5c09607
Primary Topic
Organoboron and organosilicon chemistry
Type
article
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article

Formation of Pyramidal Palladium Enhanced by B(C 6 F 5 ) 3 Additive Enabling Selective Alkene Monoisomerization

P.D. Miller, Trandon A. Bender
ACS Omega
Organoboron and organosilicon chemistry
article

Formation of Pyramidal Palladium Enhanced by B(C 6 F 5 ) 3 Additive Enabling Selective Alkene Monoisomerization

P.D. Miller, Trandon A. Bender
article en

Abstract

The addition of a strong Lewis acid, tris-(pentafluorophenyl)-borane, facilitates the reduction of Pd-(cod)-Cl<sub>2</sub> with Et<sub>3</sub>SiH to form palladium nanoparticles in organic solvents. It was found that these palladium nanoparticles are capable of selective monoisomerization of linear alkenes. This heterogeneous palladium catalyst is tolerant of a wide variety of functional groups, confirmed by substrate and robustness screenings. It is also possible to utilize poly-(methylhydro)-siloxane, an industrial waste byproduct, as the reductant to enable similar isomerization chemistry.

ACS OmegaVol. 10(50)
Old Dominion University (US)
Openalex Percentile: Top 70%
Organoboron and organosilicon chemistry
DOIOpen Access PDFOpenAlex
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Formation of Pyramidal Palladium Enhanced by B(C <sub>6</sub> F <sub>5</sub> ) <sub>3</sub> Additive Enabling Selective Alkene Monoisomerization — P.D. Miller, Trandon A. Bender · ACS Omega (2025) | TGRS Research Map | TGRS