Spectral-Based Temperature Sensing in Cr:LiCAF Crystals Using Fluorescence Peak Shift Calibration

In this study, we present a non-invasive and contactless method for estimating the internal temperature of Cr:LiCAF laser crystals using temperature-dependent shifts in fluorescence emission peaks. A high-resolution calibration dataset was created with 181 spectral points from 10 to 100 °C. Linear regression yielded a temperature estimation model with an R2 of 0.73, which was validated under both lasing and non-lasing conditions. To further evaluate the reliability of this optical thermometry method, thermal imaging data from a FLIR E75 infrared camera were incorporated. Surface temperatures measured at various diode current levels closely matched the internal temperature predictions based on fluorescence shifts (MAE = 0.775 °C, R2 = 0.993), confirming the robustness of the method. This dual-approach validation enhances confidence in using fluorescence-based diagnostics for real-time thermal monitoring in laser systems. The combined use of spectrometer-based and thermal camera measurements suggests potential for hybrid diagnostics in laser research and development, offering improved thermal feedback for optimizing high-power laser performance.