Microstructural modification and tailoring the shear mechanical properties of in-situ manufactured Mg–Si alloys via varying cooling rates during solidification

• Development of a model to determine the relation between cooling rate and microstructural features in cast Mg–Si alloys. • Plots of average grain size against the geometrical modulus ( M 2 ) followed straight lines, consistent with Chvorinov's rule. • Shear properties and hardness enhanced with increasing solidification cooling rate and adding the proper amount of Si. • The relationship between strength and hardness was obtained according to the von Mises criterion in Mg–Si alloys. The influences of silicon addition to commercially pure magnesium (CP Mg) and cooling rate during solidification on the as-cast microstructure and shear mechanical properties of Mg–Si alloys were systematically investigated. For this purpose, the Mg–0.6Si, Mg–1.34Si, and Mg–3Si (wt%) alloys were considered as hypoeutectic, eutectic, and hypereutectic alloys, respectively. By decreasing the geometrical modulus of the solidifying section (increasing cooling rate), remarkable grain refinement, refining the dendrite arm spacing (DAS), and modification of Mg 2 Si particles were achieved. Moreover, the grain size was refined via Si addition in the hypoeutectic range, while coarsening of grain size at high Si concentrations was observed. The results of shear punch testing and hardness measurements demonstrated that the ultimate shear strength (USS) and hardness increased by increasing the cooling rate during solidification. Moreover, Si addition generally improved hardness, while the highest USS level was achieved for the eutectic alloy due to the fine grain size and strengthening effect of the eutectic constituent. However, regarding the hypereutectic Mg–3Si alloy that exhibited high hardness, the shear properties were inferior due to the detrimental effect of the primary Mg 2 Si particles. Finally, the results were discussed with consideration of the relationship between strength and hardness, for which the critical effect of Si was clarified.

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Journal
Journal of Magnesium and Alloys
Published
2025-12-09
DOI
https://doi.org/10.1016/j.jma.2025.11.011
Primary Topic
Magnesium Alloys: Properties and Applications
Type
article
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article

Microstructural modification and tailoring the shear mechanical properties of in-situ manufactured Mg–Si alloys via varying cooling rates during solidification

Alireza Kalhor, Hamed Mirzadeh, Mehdi Malekan, M. Emamy et al.
Journal of Magnesium and Alloys
Magnesium Alloys: Properties and Applications
article

Microstructural modification and tailoring the shear mechanical properties of in-situ manufactured Mg–Si alloys via varying cooling rates during solidification

Alireza Kalhor, Hamed Mirzadeh, Mehdi Malekan, M. Emamy, Fatemeh Asghari
article en

Abstract

• Development of a model to determine the relation between cooling rate and microstructural features in cast Mg–Si alloys. • Plots of average grain size against the geometrical modulus ( M 2 ) followed straight lines, consistent with Chvorinov's rule. • Shear properties and hardness enhanced with increasing solidification cooling rate and adding the proper amount of Si. • The relationship between strength and hardness was obtained according to the von Mises criterion in Mg–Si alloys. The influences of silicon addition to commercially pure magnesium (CP Mg) and cooling rate during solidification on the as-cast microstructure and shear mechanical properties of Mg–Si alloys were systematically investigated. For this purpose, the Mg–0.6Si, Mg–1.34Si, and Mg–3Si (wt%) alloys were considered as hypoeutectic, eutectic, and hypereutectic alloys, respectively. By decreasing the geometrical modulus of the solidifying section (increasing cooling rate), remarkable grain refinement, refining the dendrite arm spacing (DAS), and modification of Mg 2 Si particles were achieved. Moreover, the grain size was refined via Si addition in the hypoeutectic range, while coarsening of grain size at high Si concentrations was observed. The results of shear punch testing and hardness measurements demonstrated that the ultimate shear strength (USS) and hardness increased by increasing the cooling rate during solidification. Moreover, Si addition generally improved hardness, while the highest USS level was achieved for the eutectic alloy due to the fine grain size and strengthening effect of the eutectic constituent. However, regarding the hypereutectic Mg–3Si alloy that exhibited high hardness, the shear properties were inferior due to the detrimental effect of the primary Mg 2 Si particles. Finally, the results were discussed with consideration of the relationship between strength and hardness, for which the critical effect of Si was clarified.

Journal of Magnesium and AlloysVol. 14
Silesian University of Technology (PL), University of Tehran (IR)
Openalex Percentile: Top 73%
Magnesium Alloys: Properties and Applications
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