Replicated liquid theory in 1 + <i>∞</i> dimensions

We develop a replicated liquid theory for structural glasses that exhibit spatial variation of physical quantities along one axis, say z-axis. The theory becomes exact with an infinite transverse dimension d - 1 → ∞. It provides an exact free-energy functional with a space-dependent glass order parameter Δab(z). As a first application of the scheme, we study diverging lengths associated with dynamic/static glass transitions of hard spheres with/without a confining cavity. The exponents agree with those obtained in previous studies on related mean-field models. Moreover, it predicts a non-trivial spatial profile of the glass order parameter Δab(z) within the cavity, which exhibits a scaling feature approaching the dynamical glass transition.

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Publication Details

Journal
The Journal of Chemical Physics
Published
2025-12-08
DOI
https://doi.org/10.1063/5.0300245
Primary Topic
Material Dynamics and Properties
Type
article
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article

Replicated liquid theory in 1 + ∞ dimensions

Hajime Yoshino, Yukihiro Tomita
The Journal of Chemical Physics
Material Dynamics and Properties
article

Replicated liquid theory in 1 + ∞ dimensions

Hajime Yoshino, Yukihiro Tomita
article en

Abstract

We develop a replicated liquid theory for structural glasses that exhibit spatial variation of physical quantities along one axis, say z-axis. The theory becomes exact with an infinite transverse dimension d - 1 → ∞. It provides an exact free-energy functional with a space-dependent glass order parameter Δab(z). As a first application of the scheme, we study diverging lengths associated with dynamic/static glass transitions of hard spheres with/without a confining cavity. The exponents agree with those obtained in previous studies on related mean-field models. Moreover, it predicts a non-trivial spatial profile of the glass order parameter Δab(z) within the cavity, which exhibits a scaling feature approaching the dynamical glass transition.

The Journal of Chemical PhysicsVol. 163(22)
Osaka University of Economics (JP), Osaka Prefectural Toyonaka Support School (JP), The University of Osaka (JP)
Openalex Percentile: Top 68%
Material Dynamics and Properties
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