Conformational rigidity controlled copper catalyzed chemodivergent annulation
Conformational rigidity dependent chemodivergent annulation between α-aminoketones and cyclic ethynylethylene carbonates has been developed. Reducing the amine nucleophilicity via H-bonding enabled allenal reactivity, instead of Cu-allenylidene.
Authors
- S K Panja
- Pratap Kumar Mandal (ORCID: https://orcid.org/0000-0002-8658-9295)
- Parikshit Moitra (ORCID: https://orcid.org/0000-0002-7679-7859)
- Amit Kumar Simlandy (ORCID: https://orcid.org/0000-0002-8792-4825)
- Neelam (ORCID: https://orcid.org/0000-0002-9666-6362)
- Subhra Kanti Mahato
Institutions
- Indian Institute of Science Education and Research Berhampur (IN)
Publication Details
- Journal
- Organic Chemistry Frontiers
- Published
- 2025-12-09
- DOI
- https://doi.org/10.1039/d5qo01518a
- Citations
- 1
- Primary Topic
- Catalytic C–H Functionalization Methods
- Type
- article
- Field-Weighted Citation Impact
- 0.94