Selective defluorinative [4 + 3] annulation to access fluorinated oxazepines and thiazepines

We present a powerful, metal-free annulation that directly transforms α-CF 3 -styrenes into valuable fluorinated seven-membered heterocycles, including thiazepine and oxazepine frameworks.

Authors

Institutions

Publication Details

Journal
Organic Chemistry Frontiers
Published
2025-12-09
DOI
https://doi.org/10.1039/d5qo01324k
Primary Topic
Fluorine in Organic Chemistry
Type
article
Field-Weighted Citation Impact
0.00
Controls
|||
ALL TIME
JAN
FEB
MAR
APR
MAY
JUN
JUL
AUG
SEP
OCT
article

Selective defluorinative [4 + 3] annulation to access fluorinated oxazepines and thiazepines

Keyume Ablajan, Ping Jiang, Farah Firdous, Sohail Akbar et al.
Organic Chemistry Frontiers
Fluorine in Organic Chemistry
article

Selective defluorinative [4 + 3] annulation to access fluorinated oxazepines and thiazepines

Keyume Ablajan, Ping Jiang, Farah Firdous, Sohail Akbar, Khan Shahid Ali
article en

Abstract

We present a powerful, metal-free annulation that directly transforms α-CF 3 -styrenes into valuable fluorinated seven-membered heterocycles, including thiazepine and oxazepine frameworks.

Organic Chemistry FrontiersVol. 13(3)
Xinjiang University (CN)
Openalex Percentile: Top 68%
Fluorine in Organic Chemistry
DOISourceOpenAlex
AI Navigator

Ask Laika to Summarize, Analyze, and Connect papers live on the map.

Summarize Papers & Methodologies

Extract key findings, datasets, and comparative methods across publications.

Benchmark Rankings & Visual Analytics

Rank top research institutions, authors, funders, topics, and journals by Field-Weighted Citation Impact (FWCI) and paper volume with instant charts.

Connect Distant Disciplines

Bridge topological clusters on the map to find hidden collaborative intersections.

Selective defluorinative [4 + 3] annulation to access fluorinated oxazepines and thiazepines — Keyume Ablajan, Ping Jiang, et al. · Organic Chemistry Frontiers (2025) | TGRS Research Map | TGRS