Optimizing maleic anhydride content to enhance mechanical performance and thermal stability of recycled polyolefin blends

This study evaluated the effects of maleic anhydride (MA) coupling agent on the mechanical and thermal properties and long-term stability of post-consumer recycled (PCR) plastics. The addition of MA coupling agent increased the tensile strength by 32.12%, enhancing the mechanical durability of the recycled plastic. Furthermore, the melt index (MI) increased by 366.23%, significantly improving processability. Thermogravimetric analysis (TGA) results showed a significant improvement in thermal stability, and a lifetime prediction model estimated an extension of the material's life by 532.66% at 200 °C. These results demonstrate that MA coupling agent effectively suppresses long-term degradation at high temperatures. Therefore, MA coupling agents can simultaneously improve mechanical properties and recyclability and offer a potent solution for creating sustainable plastics within a circular economy.

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Publication Details

Journal
Scientific Reports
Published
2025-12-08
DOI
https://doi.org/10.1038/s41598-025-30883-9
Primary Topic
Polymer crystallization and properties
Type
article
Field-Weighted Citation Impact
0.00

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article

Optimizing maleic anhydride content to enhance mechanical performance and thermal stability of recycled polyolefin blends

Patrick Lee, Seongeun Jang, Sung Woong Choi, Du Young Choi et al.
Scientific Reports
Polymer crystallization and properties
article

Optimizing maleic anhydride content to enhance mechanical performance and thermal stability of recycled polyolefin blends

Patrick Lee, Seongeun Jang, Sung Woong Choi, Du Young Choi, Garam Do
article en

Abstract

This study evaluated the effects of maleic anhydride (MA) coupling agent on the mechanical and thermal properties and long-term stability of post-consumer recycled (PCR) plastics. The addition of MA coupling agent increased the tensile strength by 32.12%, enhancing the mechanical durability of the recycled plastic. Furthermore, the melt index (MI) increased by 366.23%, significantly improving processability. Thermogravimetric analysis (TGA) results showed a significant improvement in thermal stability, and a lifetime prediction model estimated an extension of the material's life by 532.66% at 200 °C. These results demonstrate that MA coupling agent effectively suppresses long-term degradation at high temperatures. Therefore, MA coupling agents can simultaneously improve mechanical properties and recyclability and offer a potent solution for creating sustainable plastics within a circular economy.

Scientific ReportsVol. 16(1)
Jeonju National University of Education (KR), University of Toronto (CA), Jeonbuk National University (KR), Korea Institute of Science & Technology Information (KR), Korea Institute of Industrial Technology (KR)
Korea Institute of Industrial Technology, National Research Council of Science and Technology, Ministry of Science and ICT, South Korea, Natural Sciences and Engineering Research Council of Canada
Openalex Percentile: Top 65%
Polymer crystallization and properties
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