Synthesis and Spectral Characteristics of Copper Complexes Based on Pectin Modified with L-Arginine, L-Alanine, and L-Aspartic Acid

Polymer ligands based on apple pectin modified with amino acids (L-arginine, L-alanine, and L‑aspartic acid) were synthesized and characterized by IR and 13C NMR spectroscopy, polarimetry, viscometry, and elemental analysis. Based on the synthesized polymer ligands, new metal-polymer complexes of copper(II) were synthesized:. The stoichiometry of the resulting metal complexes and the pH ranges of their existence were determined using the spectrophotometric method and elemental analysis data. It has been established that the modification of pectin with amino acids increases the stability of copper-containing polymer complexes compared to their homoligand analogs in a medium simulating gastric juice.

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Journal
Russian Journal of Physical Chemistry A
Published
2025-12-01
DOI
https://doi.org/10.1134/s003602442570253x
Primary Topic
Polysaccharides and Plant Cell Walls
Type
article
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article

Synthesis and Spectral Characteristics of Copper Complexes Based on Pectin Modified with L-Arginine, L-Alanine, and L-Aspartic Acid

�. A. Vakhitova, Р. Х. Мударисова, Igor Novoselov
Russian Journal of Physical Chemistry A
Polysaccharides and Plant Cell Walls
article

Synthesis and Spectral Characteristics of Copper Complexes Based on Pectin Modified with L-Arginine, L-Alanine, and L-Aspartic Acid

�. A. Vakhitova, Р. Х. Мударисова, Igor Novoselov
article en

Abstract

Polymer ligands based on apple pectin modified with amino acids (L-arginine, L-alanine, and L‑aspartic acid) were synthesized and characterized by IR and 13C NMR spectroscopy, polarimetry, viscometry, and elemental analysis. Based on the synthesized polymer ligands, new metal-polymer complexes of copper(II) were synthesized:. The stoichiometry of the resulting metal complexes and the pH ranges of their existence were determined using the spectrophotometric method and elemental analysis data. It has been established that the modification of pectin with amino acids increases the stability of copper-containing polymer complexes compared to their homoligand analogs in a medium simulating gastric juice.

Russian Journal of Physical Chemistry AVol. 99(12)
Ufa Institute of Chemistry (RU), Ufa State Petroleum Technological University (RU)
Openalex Percentile: Top 72%
Polysaccharides and Plant Cell Walls
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Synthesis and Spectral Characteristics of Copper Complexes Based on Pectin Modified with L-Arginine, L-Alanine, and L-Aspartic Acid — �. A. Vakhitova, Р. Х. Мударисова, et al. · Russian Journal of Physical Chemistry A (2025) | TGRS Research Map | TGRS