Bis(1,2,4-triphenylcyclopentadienyl) Terbium 4,4,4-trifluoro-1-phenylbutane-1,3-dionate
A new bis(cyclopentadienyl) terbium(III) complex with 1,2,4-triphenylcyclopentadienyl and 4,4,4-trifluoro-1-phenylbutane-1,3-dionate ligands was synthesized. Single-crystal X-ray analysis revealed a mononuclear bis(cyclopentadienyl) complex with a diketonate ligand in the bisector plane. The compound under study exhibits a ligand ligand charge transfer state (LLCT), according to optical spectroscopy and crystallographic data.
Authors
- Ilya E. Nifant’ev (ORCID: https://orcid.org/0000-0001-9151-1890)
- Mikhail Evgenievich Minyaev (ORCID: https://orcid.org/0000-0002-4089-3697)
- Daniil A. Bardonov (ORCID: https://orcid.org/0009-0001-1052-3599)
- Dmitrii M. Roitershtein (ORCID: https://orcid.org/0000-0003-0320-1775)
- Lada N. Puntus
Institutions
- Plekhanov Russian University of Economics (RU)
- National Research University Higher School of Economics (RU)
- Russian Academy of Sciences (RU)
- Lomonosov Moscow State University (RU)
- N.D. Zelinsky Institute of Organic Chemistry (RU)
- A.V. Topchiev Institute of Petrochemical Synthesis (RU)
- Kotelnikov Institute of Radioengineering and Electronics of the Russian Academy of Sciences (RU)
Publication Details
- Journal
- Molbank
- Published
- 2025-12-04
- DOI
- https://doi.org/10.3390/m2102
- Primary Topic
- Organometallic Complex Synthesis and Catalysis
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Ministry of Science and Higher Education of the Russian Federation