Synthesis, and structural and photophysical studies of mono- and dinuclear alkali metal 2,6-dibenzhydryl-4-methylphenolates

A series of dinuclear alkali metal 2,6-dibenzhydryl-4-methylphenolates [Ar*OM(THF)] 2 (Ar* = 2,6-(Ph 2 CH) 2 -4-MeC 6 H 2 -; M1, M = Li, Na, K) were isolated from the reaction of metal bis(trimethylsilyl)amides with Ar*OH phenol in the THF medium.

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Publication Details

Journal
New Journal of Chemistry
Published
2025-12-08
DOI
https://doi.org/10.1039/d5nj03734d
Primary Topic
Synthesis and characterization of novel inorganic/organometallic compounds
Type
article
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article

Synthesis, and structural and photophysical studies of mono- and dinuclear alkali metal 2,6-dibenzhydryl-4-methylphenolates

Darina I. Nasyrova, Mikhail Evgenievich Minyaev, Daniil A. Bardonov, Dmitrii M. Roitershtein et al.
New Journal of Chemistry
Synthesis and characterization of novel inorganic/organometallic compounds
article

Synthesis, and structural and photophysical studies of mono- and dinuclear alkali metal 2,6-dibenzhydryl-4-methylphenolates

Darina I. Nasyrova, Mikhail Evgenievich Minyaev, Daniil A. Bardonov, Dmitrii M. Roitershtein, Ilya V. Taydakov, Mikhail T. Metlin
article en

Abstract

A series of dinuclear alkali metal 2,6-dibenzhydryl-4-methylphenolates [Ar*OM(THF)] 2 (Ar* = 2,6-(Ph 2 CH) 2 -4-MeC 6 H 2 -; M1, M = Li, Na, K) were isolated from the reaction of metal bis(trimethylsilyl)amides with Ar*OH phenol in the THF medium.

New Journal of ChemistryVol. 50(3)
National Research University Higher School of Economics (RU), P.N. Lebedev Physical Institute of the Russian Academy of Sciences (RU), Russian Academy of Sciences (RU), Moscow Institute of Physics and Technology (RU), Bauman Moscow State Technical University (RU), N.D. Zelinsky Institute of Organic Chemistry (RU), A.V. Topchiev Institute of Petrochemical Synthesis (RU)
Openalex Percentile: Top 67%
Synthesis and characterization of novel inorganic/organometallic compounds
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