Asymmetric hydrogenation of ketones with planar chiral manganese( <scp>i</scp> ) complexes
Manganese complexes bearing ferrocenyl ligands with only planar chirality catalyse the hydrogenation of aromatic ketones under mild conditions: 30 °C, 30 bar H 2 , K 2 CO 3 , EtOH, down to 0.1 mol% manganese, with up to 69% ee.
Authors
- Agnès Labande (ORCID: https://orcid.org/0000-0003-0192-2499)
- Éric Manoury (ORCID: https://orcid.org/0000-0001-7991-8890)
- Rui Yang (ORCID: https://orcid.org/0000-0002-9175-7791)
- Sonia Mallet‐Ladeira (ORCID: https://orcid.org/0009-0004-2446-6697)
- Uchchhal Bandyopadhyay (ORCID: https://orcid.org/0000-0002-1429-7373)
- Rinaldo Poli (ORCID: https://orcid.org/0000-0002-5220-2515)
Institutions
- Centre National de la Recherche Scientifique (FR)
- Université Toulouse III - Paul Sabatier (FR)
- Université Fédérale de Toulouse Midi-Pyrénées (FR)
- Institut Universitaire de France (FR)
- Institut National Polytechnique de Toulouse (FR)
- Laboratoire de Chimie de Coordination (FR)
Publication Details
- Journal
- New Journal of Chemistry
- Published
- 2025-12-03
- DOI
- https://doi.org/10.1039/d5nj03919c
- Citations
- 1
- Primary Topic
- Asymmetric Hydrogenation and Catalysis
- Type
- article
- Field-Weighted Citation Impact
- 0.54