High-temperature evolution and deformation behavior of residual modified Al2O3 inclusions in Si-killed and Ce-treated GCr15 bearing steel

Cerium treatment was used to modify residual Al 2 O 3 inclusions in Si-killed GCr15 bearing steel, and high-temperature evolution and deformation behavior of these residual inclusions were studied to assess their harmfulness. The results indicated cerium treatment can modify Al 2 O 3 , SiO 2 and MnS inclusions in as-cast Ce-free steel (S0) into finer, near-spherical Ce–S–Al–O composite inclusions in Ce-treated steel (S1, 0.017 wt% Ce). During isothermal heating at 1473 K for 120 min, these initially glassy Ce–S–Al–O composite inclusions in as cast S1 steel evolved into Ce 2 S 3 (core)–Al 2 O 3 (shell) multiphase composite inclusions by crystallization, which is attributed to first precipitation of the thermodynamically more stable Ce 2 S 3 at the core of the inclusions and to outward diffusion of aluminum and oxygen atoms due to the repulsive effect of Ce 2 S 3 crystals, froming an Al 2 O 3 shell layer with crescent moon shape on the inclusion surface. Gleeble hot-compression simulations revealed that the deformation index (ν) of inclusions in Ce-treated steel S1 (average ν ≈ 0.36) is significantly lower than that in Ce-free steel S0 (average ν ≈ 0.67), mainly because of the higher toughness of Ce 2 S 3 (core) compared to MnS in S0 steel and the restraining deformation effect of the rigid Al 2 O 3 shell of the dual phase inclusions in S1 steel. The coordination deformation of Ce 2 S 3 (core)–Al 2 O 3 (shell) composite inclusions in steel significantly reduced stress brittleness of Al 2 O 3 shell like single polygonal Al 2 O 3 inclusions during hot-deformation process, the fatigue performance of the tested steel still needs to be further verified.

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Journal
Journal of Materials Research and Technology
Published
2025-12-06
DOI
https://doi.org/10.1016/j.jmrt.2025.12.056
Primary Topic
Microstructure and Mechanical Properties of Steels
Type
article
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article

High-temperature evolution and deformation behavior of residual modified Al2O3 inclusions in Si-killed and Ce-treated GCr15 bearing steel

Yi‐Chun Zhu, Guangqiang Li, Jing Liu, Dongming Liu et al.
Journal of Materials Research and Technology
Microstructure and Mechanical Properties of Steels
article

High-temperature evolution and deformation behavior of residual modified Al2O3 inclusions in Si-killed and Ce-treated GCr15 bearing steel

Yi‐Chun Zhu, Guangqiang Li, Jing Liu, Dongming Liu, Zirui Yan, Wan Zheng
article en

Abstract

Cerium treatment was used to modify residual Al 2 O 3 inclusions in Si-killed GCr15 bearing steel, and high-temperature evolution and deformation behavior of these residual inclusions were studied to assess their harmfulness. The results indicated cerium treatment can modify Al 2 O 3 , SiO 2 and MnS inclusions in as-cast Ce-free steel (S0) into finer, near-spherical Ce–S–Al–O composite inclusions in Ce-treated steel (S1, 0.017 wt% Ce). During isothermal heating at 1473 K for 120 min, these initially glassy Ce–S–Al–O composite inclusions in as cast S1 steel evolved into Ce 2 S 3 (core)–Al 2 O 3 (shell) multiphase composite inclusions by crystallization, which is attributed to first precipitation of the thermodynamically more stable Ce 2 S 3 at the core of the inclusions and to outward diffusion of aluminum and oxygen atoms due to the repulsive effect of Ce 2 S 3 crystals, froming an Al 2 O 3 shell layer with crescent moon shape on the inclusion surface. Gleeble hot-compression simulations revealed that the deformation index (ν) of inclusions in Ce-treated steel S1 (average ν ≈ 0.36) is significantly lower than that in Ce-free steel S0 (average ν ≈ 0.67), mainly because of the higher toughness of Ce 2 S 3 (core) compared to MnS in S0 steel and the restraining deformation effect of the rigid Al 2 O 3 shell of the dual phase inclusions in S1 steel. The coordination deformation of Ce 2 S 3 (core)–Al 2 O 3 (shell) composite inclusions in steel significantly reduced stress brittleness of Al 2 O 3 shell like single polygonal Al 2 O 3 inclusions during hot-deformation process, the fatigue performance of the tested steel still needs to be further verified.

Journal of Materials Research and TechnologyVol. 41
Wuhan University of Science and Technology (CN)
Openalex Percentile: Top 60%
Microstructure and Mechanical Properties of Steels
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