Biligand synergistic MOFs with dual enhancements in stability and charge transfer for efficient CO <sub>2</sub> photoreduction
Herein, biligand synergistic metal-organic frameworks were prepared. The optimized UiO-67-CF<sub>3</sub>-50 simultaneously exhibits excellent thermal and chemical stability. Benefiting from facilitated charge transfer, UiO-67-CF<sub>3</sub>-50 achieves a significantly enhanced CO yield of 907.0 µmol g<sup>-1</sup> from CO<sub>2</sub> photoreduction, 1.8 and 5.2 times higher than those of the single-ligand UiO-67-CF<sub>3</sub>-100 and UiO-67-CF<sub>3</sub>-0, respectively.
Authors
- Xiahe Chen
- Yongpeng Ouyang (ORCID: https://orcid.org/0000-0001-8930-2475)
- Yun‐Fang Yang (ORCID: https://orcid.org/0000-0002-6287-1640)
- Junze Zhao
- Jiexiang Xia (ORCID: https://orcid.org/0000-0002-7394-1130)
- Yuanbin She (ORCID: https://orcid.org/0000-0002-1007-1852)
- Yi Zhang (ORCID: https://orcid.org/0000-0003-4769-6642)
- Keke Wang (ORCID: https://orcid.org/0000-0002-2227-8471)
- Huaming Li (ORCID: https://orcid.org/0000-0002-9538-5358)
- Kai Zhang (ORCID: https://orcid.org/0000-0001-5058-9077)
- Jiayin Tao
- Qin Wang (ORCID: https://orcid.org/0000-0002-2118-8343)
- Bolin Zhou (ORCID: https://orcid.org/0009-0002-6015-1743)
Institutions
- Jiangsu University (CN)
- Hong Kong Polytechnic University (HK)
- State Key Laboratory of Chemical Engineering (CN)
- Zhejiang University of Technology (CN)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-11-21
- DOI
- https://doi.org/10.1039/d5cc05401j
- Primary Topic
- Advanced Photocatalysis Techniques
- Type
- article
- Field-Weighted Citation Impact
- 0.00