Shape-specific fluctuations of an active colloidal interface

Motivated by a recently synthesizable class of active interfaces formed by linked self-propelled colloids, we investigate the dynamics and fluctuations of a phoretically (chemically) interacting active interface with roto-translational coupling. We enumerate all steady-state shapes of the interface across parameter space and identify a regime where the interface acquires a finite curvature, leading to a characteristic "C-shaped" topology, along with persistent self-propulsion. In this phase, the interface height fluctuations obey Family-Vicsek scaling but with novel exponents: a dynamic exponent zh ≈ 0.5, a roughness exponent αh ≈ 0.9, and a super-ballistic growth exponent βh ≈ 1.7. In contrast, the orientational fluctuations of the colloidal monomers exhibit a negative roughness exponent, reflecting a surprising smoothness law, where steady-state fluctuations diminish with increasing system size. Together, these findings point toward a unique non-equilibrium universality class associated with self-propelled interfaces of non-standard shape.

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Publication Details

Journal
The Journal of Chemical Physics
Published
2026-01-21
DOI
https://doi.org/10.1063/5.0301699
Primary Topic
Micro and Nano Robotics
Type
article
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article

Shape-specific fluctuations of an active colloidal interface

Arvin Gopal Subramaniam, Rajesh Singh, Tirthankar Banerjee
The Journal of Chemical Physics
Micro and Nano Robotics
article

Shape-specific fluctuations of an active colloidal interface

Arvin Gopal Subramaniam, Rajesh Singh, Tirthankar Banerjee
article en

Abstract

Motivated by a recently synthesizable class of active interfaces formed by linked self-propelled colloids, we investigate the dynamics and fluctuations of a phoretically (chemically) interacting active interface with roto-translational coupling. We enumerate all steady-state shapes of the interface across parameter space and identify a regime where the interface acquires a finite curvature, leading to a characteristic "C-shaped" topology, along with persistent self-propulsion. In this phase, the interface height fluctuations obey Family-Vicsek scaling but with novel exponents: a dynamic exponent zh ≈ 0.5, a roughness exponent αh ≈ 0.9, and a super-ballistic growth exponent βh ≈ 1.7. In contrast, the orientational fluctuations of the colloidal monomers exhibit a negative roughness exponent, reflecting a surprising smoothness law, where steady-state fluctuations diminish with increasing system size. Together, these findings point toward a unique non-equilibrium universality class associated with self-propelled interfaces of non-standard shape.

The Journal of Chemical PhysicsVol. 164(3)
University of Luxembourg (LU), Indian Institute of Technology Madras (IN)
Openalex Percentile: Top 97%
Micro and Nano Robotics
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Shape-specific fluctuations of an active colloidal interface — Arvin Gopal Subramaniam, Rajesh Singh, et al. · The Journal of Chemical Physics (2026) | TGRS Research Map | TGRS